Loading...
HomeMy WebLinkAboutRICHIE'S EXPRESS CARWASH - PDP - 15-00 - SUBMITTAL DOCUMENTS - ROUND 1 - HAZMATSSECTION X DOT SHIPPING INFORMATION DOT Shipping Name: Compound cleaning liquid (contains ethanolamine) PG III, 8, NA — 1760 Label Requirements: CORROSIVE DOT Hazardous Substance CAS Number None NA Reportable Quantity (RQ) NA The information presented herein is based on data considered to be accurate as of the date of preparation of this Material Safety Data Sheet. However, no warranty or representation, expressed or implied, is made as to the accuracy or completeness of the foregoing data and safety information. In addition, no responsibility can be assumed by vendor for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices, or from any hazards inherent in the nature of the product. SECTION V REACTIVITY DATA Stability Stable Conditions and Materials to Avoid Alkalis, oxidizers, and most metals Hazardous Decomposition or By -Products Thermal decomposition may release corrosive phosphoric oxide fumes and acid mist. Polymerization Will not occur Conditions to Avoid None known SECTION VI HEALTH HAZARD DATA Inhalation Acute CORROSIVE: Inhalation may cause choking, coughing, and irritation of the throat. Ulceration of the nose, throat, or larynx, bronchitis, pneumonia, palpitations, and headache. Chronic Repeated or prolonged exposure may cause erosion and discoloration of exposed teeth, chronic bronchitis and gastritis. Eye Contact Acute CORROSIVE: Contact may cause severe irritation, conjunctivitis, corneal necrosis and bums with impairment or permanent loss of vision. Clouding or corrosion of the cornea. Chronic Effects are dependent on concentration and duration. See acute exposure. Skin contact Acute CORROSIVE: Contact may cause severe irritation, inflammation, ulceration, necrosis, and chemical burns. Chronic Repeated or prolonged contact with vapors or dilute solutions may cause dermatitis or slow healing chemical burns. Photosensitization may occur. Ingestion Acute CORROSIVE: May cause bums of the mouth, throat, esophagus and stomach with consequent pain, uneasiness nausea, salivation, vomiting, diarrhea, chills, shock and intense thirst. Chronic No data available Medical Conditions Aggravated By Exposure None known Chemical Listed as Carcinogen or Potential Carcinogen No National Toxicology Program I.A.R.C. Monographs: NO OSHA: NO ROUTES OF ENTRY/EMERGENCY AND FIRST AID PROCEDURES Inhalation Remove to fresh air. If breathing has stopped, give artificial respiration. Get medical attention. Even in the absence of symptoms, a worker must not be permitted to return to work for at least 24 hours. Eyes: Rinse eyes with large amounts of cool water for 15-20 minutes lifting upper and lower lids. Rinse with saline solution until the pH is back to normal (30-60 minutes) Get Medical Attention preferably an eye specialist. Skin: Remove contaminated clothing. Wash off with soap and large amounts of water. Use a good skin emollient. If skin is burned, cover with a sterile dry dressing and seek Medical Attention. Ingestion: Do not use gastric lavage or emesis. Dilute acid immediately by drinking large amounts of water or milk. Ingested acid must be diluted 100 fold to render it harmless. Get Medical Attention. SECTION VII PRECAUTIONS FOR SAFE HANDLING AND USE Precautions To Be Taken In Handling and Storage: Keep product from freezing. If frozen, thaw & agitate before use. Other Precautions : None Steps To Be Taken In Case Material Is Released Or Spilled: Large Spills: Dike and contain for intended use. Small Spills: Flush with water down the sewer Waste Disposal Method: Follow all Local, State, and Federal Regulations in your area. SECTION VIII OTHER REGULATORY INFORMATION SECTION 313 (With Chemicals Listed): This product contains the following toxic chemical(s) subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA) and 40 CFR Part 372: Ingredient None CAS Number NA Weight Percent NA SECTION IX SPECIAL PROTECTION & CONTROL MEASURES RESPIRATORY PROTECTION: None VENTILATION: Local Exhaust Mechanical Special Other xxx Protective Gloves: Rubber Eye Protection: Goggles Other Protective Clothing or Equipment: None Work/Hygiene Practices : Keep off of clothing SECTION X DOT SHIPPING INFORMATION DOT Shipping Name: Combustible liquid, n.o.s. (Contains Isopropyl Alcohol), 3, PG III, NA 1993 Label Requirements: NONE DOT Hazardous Substance CAS Number None NA Reportable Quantity (RQ) NA The information presented herein is based on data considered to be accurate as of the date of preparation of this Material Safety Data Sheet. However, no warranty or representation, expressed or implied, is made as to the accuracy or completeness of the foregoing data and safety information. In addition, no responsibility can be assumed by vendor for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices, or from any hazards inherent in the nature of the product. 3 DOT Shipping Name: Label Requirements: SECTION X DOT SHIPPING INFORMATION Compound cleaning liquid, n.o.s. (contains hydrochloric, phosphoric acids) PG 11, NA 1760 CORROSIVE DOT Hazardous Substance CAS Number Hydrochloric Acid 7647-01-0 Phosphoric Acid 7664-38-2 Reportable Quantity (RQ) 50001bs. 5000 lbs. The information presented herein is based on data considered to be accurate as of the date of preparation of this Material Safety Data Sheet. However, no warranty or representation, expressed or implied, is made as to the accuracy or completeness of the foregoing data and safety information. In addition, no responsibility can be assumed by vendor for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices, or from any hazards inherent in the nature of the product. SECTION VII PRECAUTIONS FOR SAFE HANDLING AND USE Precautions To Be Taken In Handling and Storage: Store in a cool well -ventilated place, separated from all oxidizing materials. Other Precautions : Store away from incompatible substances. Steps To Be Taken In Case Material Is Released Or Spilled: Persons not wearing protective clothing must be restricted from area until clean-up is complete. Dike flow of spilled material using soil or spill kits. Small amounts of acid may be flushed with large amounts of water. Large spills can be neutralized with Lime. Waste Disposal Method: Follow all Local, State, and Federal Regulations in your area. SECTION VIII OTHER REGULATORY INFORMATION SECTION 313 (With Chemicals Listed): This product contains the following toxic chemical(s) subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA) and 40 CFR Part 372: Ingredient Hydrochloric Acid Phosphoric Acid CAS Number 7647-01-0 7664-38-2 Weight Percent 2-5% 4-7% SECTION IX SPECIAL PROTECTION & CONTROL MEASURES RESPIRATORY PROTECTION: U.S. Bureau of Mines Respirator; self contained breathing device, airline or NIOSH approved respirator. The specific respirator selected must be based on contamination levels in the work place, must be based on the specific operation, must not exceed the working limits of the respirator, and must be jointly approved by the National Institute of Occupational Safety and Health and the Mine Safety and Health Administration (NIOSH-MSHA). VENTILATION: Local Exhaust Mechanical Special Other xxx Protective Gloves: Heavy PVC gaunlet gloves Eye Protection: Splash -proof or dust resistant safety goggles and a faceshield to prevent contact with this substance. Other Protective Clothing or Equipment: Appropriate protective (impervious) clothing and equipment to prevent contact with this substance. Eyewashes and drench showers should be in the immediate work area. Work/Hygiene Practices: Keep off of clothing Stability Conditions and Materials to Avoid SECTION V REACTIVITY DATA Stable Alkalis, oxidizers, and most metals Hazardous Decomposition or By -Products Thermal decomposition may release corrosive phosphoric oxide, corrosive hydrogen chloride fumes and acid mist. Polymerization Conditions to Avoid Will not occur None known SECTION VI HEALTH HAZARD DATA Inhalation Acute CORROSIVE: 100ppm immediately dangerous to life or health. Inhalation of 5-35ppms may cause choking, coughing, and irritation of the throat. Ulceration of the nose, throat, or larynx, bronchitis, pneumonia, palpitations, and headache. Chronic Repeated or prolonged exposure may cause erosion and discoloration of exposed teeth, chronic bronchitis and gastritis. Eye Contact Acute CORROSIVE: Contact may cause severe irritation, conjunctivitis, corneal necrosis and bums with impairment or permanent loss of vision. Clouding or corrosion of the comea. Contact with a compressed gas may cause frostbite. Chronic Effects are dependent on concentration and duration. See acute exposure. Skin contact Acute CORROSIVE: contact may cause severe irritation, inflammation, ulceration, necrosis, and chemical bums. Chronic Repeated or prolonged contact with vapors or dilute solutions may cause dermatitis. Photosensitization may occur. Ingestion Acute CORROSIVE: May cause bums of the mouth, throat, esophagus and stomach with consequent pain, uneasiness nausea, salivation, vomiting, diarrhea, chills, shock and intense thirst. Chronic No data available Medical Conditions Aggravated By Exposure None known Chemical Listed as Carcinogen or Potential Carcinogen No National Toxicology Program I.A.R.C. Monographs: NO OSHA: NO ROUTES OF ENTRY/EMERGENCY AND FIRST AID PROCEDURES Inhalation Remove to fresh air. If breathing has stopped, give artifical respiration. Get medical attention. Even in the absence of symptoms, a worker must not be permitted to return to work for at least 24 hours. Eyes: Rinse eyes with large amounts of cool water for 15-20 minutes lifting upper and lower lids. Rinse with saline solution until the pH is back to normal (30-60 minutes) Get Medical Attention preferably an eye specialist. Skin: Remove contaminated clothing. Wash off with soap and large amounts of water. Use a good skin emollient. If skin is burned, cover with a sterile dry dressing and seek Medical Attention. Ingestion: Do not use gastric lavage or emesis. Dilute acid immediately by drinking large amounts of water or milk. Ingested acid must be diluted 100 fold to render it harmless. Get Medical Attention. 1viATERIAL SAFETY DATA SHEL f SECTION I SUPPLIER INFORMATION Common Name: Wheel Prep Chemical Name: Formula: Supplier: Magic Investments Inc. 427 Mount Lebanon Boulevard Pittsburgh, PA 15234 Phone: (412) 343 — 3555 Emergency Phone: Chem -Tel I-800-255-3924 (24 hours) Date Prepared: Monday, February 21, 2000 SECTION II HAZARDOUS INGREDIENT INFORMATION CFR 29 Part 19 10. 1000 Table Z-I (July 1, 1998 issue) Ingredient CAS Number PEL-OSHA TWA -OSHA TLV-ACGIH STEL-ACGIH (ppm) (ml/m) (PPm) (ppm) Phosphoric Acid 7664-38-2 1 (mg/m) 1 1 (mg/m) 3 (mg/m3) Hydrochloric Acid 7647-01-0 5 7.5 5 10 SECTION III PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: 212 of Specific Gravity: 1.1 Melting Point: N/A of PH: <1 Vapor Pressure (mm Hg): N/A Vapor Density (Air-1): N/A Evaporation Rate (Butyl Acetate =1): N/A Solubility in Water: 100% Appearance and Odor: A clear liquid with a mild acid odor. SECTION IV FIRE AND EXPLOSION HAZARD DATA Flash Point: none of Auto -Ignition Temperature: none of LEL: NA % UEL: NA % Extinguisher Media: This material does not support combustion. Use CO2, Dry Chemical, Foam Extinguisher or water spray. Do not use solid water streams. Phosphoric Acid reacts violently with water and can splatter personnel. Special Fire Fighting Procedures: Can give off noxious fumes when heated. Use SCBA Firefighters should wear NIOSH approved self-contained acid suits Unusual Fire and Explosion Hazards: HCI gas and phosphorus oxide gas can be driven off of solutions SECTION VII PRECAUTIONS FOR SAFE HANDLING AND USE Precautions To Be Taken In Handling and Storage: Keep product from freezing. Other Precautions: None Steps To Be Taken In Case Material Is Released Or Spilled: Large Spills: Dike and contain for intended use. Small Spills: Pick up with inert absorbant and place in closed container for disposal. Waste Disposal Method: Follow all Local, State, and Federal Regulations in your area. SECTION VIII OTHER REGULATORY INFORMATION SECTION 313 (With. Chemicals Listed): This product contains the following toxic chemical(s) subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA) and 40 CFR Part 372: Ingredient None CAS Number NA Weight Percent NA SECTION IX SPECIAL PROTECTION & CONTROL MEASURES RESPIRATORY PROTECTION: The specific respirator selected must be based on contamination levels in the work place, must be based on the specific operation, must not exceed the working limits of the respirator, and must be jointly approved by the National Institute of Occupational Safety and Health and the Mine Safety and Health Administration (NIOSH-MSHA). VENTILATION: Local Exhaust Mechanical Special xxx Protective Gloves: Nitrite, neoprene or other material resistant to distillate. Eye Protection: Safety glass, chemical goggles of face shield as appropriate. Other Protective Clothing or Equipment: None Work/Hygiene Practices: Keep off of clothing SECTION X DOT SHIPPING INFORMATION Other DOT Shipping Name: Toxic, liquids organic, n.o.s. (Contains Ethylene Glycol Monobutyl Ether), 6.1, PG III, UN - 2810 Label Requirements: KEEP AWAY FROM FOOD DOT Hazardous Substance CAS Number Acetic Acid 64-19-7 Reportable Quantity (RQ) 5000 lbs. The information presented herein is based on data considered to be accurate as of the date of preparation of this Material Safety Data Sheet. However, no warranty or representation, expressed or implied, is made as to the accuracy or completeness of the foregoing data and safety information. In addition, no responsibility can be assumed by vendor for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices, or from any hazards inherent in the nature of the product. SECTION V REACTIVITY DATA Stability Stable Conditions and Materials to Avoid Very high temperatures Hazardous Decomposition or By -Products Incomplete combustion can yield carbon monoxide and various hydrocarbons Polymerization None Conditions to Avoid None known SECTION VI HEALTH HAZARD DATA Inhalation Acute Headache, nasal and respiratory irritation, nausea, drowsiness, breathlessness, fatigue, central nervous system depression, convulsions, and loss of consciousness. Chronic Eye Contact Acute Irritation Chronic Skin Contact Acute May cause slight reddening and/or irritation Chronic Long exposure may defat skin. Ingestion Acute Aspiration hazard, headache, nausea, drowsiness, fatigue, pneumonitis, pulmonary edema, central nervous system depression, convulsions and loss of consciousness, blindess, and even death. Chronic Medical Conditions Aggravated By Exposure None known Chemical Listed as Carcinogen or Potential Carcinogen No National Toxicology Program No I.A.R.C. Monographs: No OSHA: No ROUTES OF ENTRY/EMERGENCY AND FIRST AID PROCEDURES Inhalation Remove to fresh air Eyes: Rinse Eyes With Cool Water For 15 minutes, occasionally lifting the lower and upper lids. If stinging persists, get medical attention. Skin: Wash off with soap and water. Ingestion: Call a physician immediately, ONLY induce vomitting at the instruction of a physician. Never give anything by mouth to an unconscious person. 1v.ATERIAL SAFETY DATA SIAEL i' SECTION I SUPPLIER INFORMATION Common Name: Fahrvergnugen - D - Magic Blend Chemical Name: Formula: Supplier: Magic Investments 427 Mount Lebanon Boulevard Pittsburgh, PA 15234 Phone: (412)343-3555 Emergency Phone: Chem -Tel 1-800-255-3924 (24 hours) Date Prepared Monday, February 21, 2000 SECTION II HAZARDOUS INGREDIENT INFORMATION CFR 29 Part 1910.1000 Table Z-1 (July 1, 1998 issue) Ingredient CAS Number PEL-OSHA TWA -OSHA TLV-ACGIH STEL-ACGIH (PPm) (mg/m) (PPm) (ppm) Butoxyethanol 111-76-2 25 121 25 Mineral Seal Oil 64741-44-2 Acetic Acid 64-19-7 10 25 15 Isopropyl Alcohol 67-63-0 400 983 500 SECTION III PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: Specific Gravity: Melting Point: pH: Vapor Pressure (nun Hg): Vapor Density (Air-1): Evaporation Rate (Butyl Acetate =1): Solubility in Water: Appearance and Odor: Flash Point: Auto -Ignition Temperature: LEL: UEL: Extinguisher Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: 212 of 0.88 N/A of 4-6 N/A N/A N/A Complete Amber liquid with a vinegar odor SECTION IV FIRE AND EXPLOSION HAZARD DATA N/A of N/A of N/A % N/A % This material does not support combustion. Use COZ, Dry Chemical, Foam Extinguisher or water spray. Use water spray only to cool containers exposed to fire. Use water to disperse vapors. Can form combustible mixtures with air when heated The information presented herein is baseu on data considered to be accurate as of the date of preparation of this Material Safety Data Sheet. However, no warranty or representation, expressed or implied, is made as to the accuracy or completeness of the foregoing data and safety information. In addition, no responsibility can be assumed by vendor for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices, or from any hazards inherent in the nature of the product. SECTION VII PRECAUTIONS FOR SAFE HANDLING AND USE Precautions To Be Taken In Handling and Storage: Store in a cool well -ventilated place, separated from all oxidizing materials. Other Precautions: Store away from incompatible substances. Steps To Be Taken In Case Material Is Released Or Spilled: Persons not wearing protective clothing must be restricted from area until clean up is complete. Dike flow of spilled material using soil or spill kits. Small amounts of acid may be flushed with large amounts of water. Large spills can be neutralized with Lime. Waste Disposal Method: Follow all Local, State and Federal Regulations in your area. SECTION VIII OTHER REGULATORY INFORMATION SECTION 313 (With Chemicals Listed): This product contains the following toxic chemical(s) subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA) and 40 CFR Part 372: Ingredient None CAS Number NA Weight Percent NA SECTION IX SPECIAL PROTECTION & CONTROL MEASURES RESPIRATORY PROTECTION: U.S. Bureau of Mines Respirator; self-contained breathing device, airline or NIOSH approved respirator. The specific respirator selected must be based on contamination levels in the work place, must be based on the specific operation, must not exceed the working limits of the respirator, and must be jointly approved by the National Institute of Occupational Safety and Health and the Mine Safety and Health Administration (NIOSH-MSHA). VENTILATION: Local Exhaust Mechanical Special Other Xxx Protective Gloves: Heavy PVC gaunlet gloves Eye Protection: Splash -proof or dust resistant safety goggles and a faceshield to prevent contact with this substance. Other Protective Clothing or Equipment: Appropriate protective (impervious) clothing and equipment to prevent contact with this substance. Eyewashes and drench showers should be in the immediate work area. Work/Hygiene Practices : Keep off of clothing kYXiyti(i]J:��Ziy1l.�:ii;a3l.LHi`►i�i17��I:��(i],I DOT Shipping Name: Compound cleaning liquid, n.o.s. (contains acetic acid) PG III, NA 1760 Label Requirements: CORROSIVE DOT Hazardous Substance CAS Number Reportable Quantity (RQ) Acetic Acid 64-19-7 5000 lbs. i,-t-TERIAL SAFETY DATA SHEL, SECTION I SUPPLIER INFORMATION Common Name: Special Mix = A Chemical Name: Formula: Supplier: Magic Investments Inc. 427 Mount Lebanon Boulevard Pittsburgh, PA 15234 Phone: (412) 343 — 3555 Emergency Phone: Chem -Tel 1-800-255-3924 (24 hours) Date Prepared: Monday, February 21, 2000 SECTION II HAZARDOUS INGREDIENT INFORMATION CFR 29 Part 1910.1000 Table Z-1 (July 1, 1998 issue) Ingredient CAS Number PEL-OSHA TWA -OSHA TLV-ACGIH STEL-ACGIH (ppm) (mg/in) (ppm) (ppm) Acetic Acid 64-19-7 10 25 10 15 SECTION III PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: 212 of Specific Gravity: 1.04 Melting Point: N/A of pH: <1 Vapor Pressure (nun Hg): N/A Vapor Density (Air-- N/A Evaporation Rate (Butyl Acetate =1): N/A Solubility in Water: 100% Appearance and Odor: A clear liquid with a strong vinegar odor. SECTION IV FIRE AND EXPLOSION HAZARD DATA Flash Point: None of Auto -Ignition Temperature: None of LEL: NA % UEL: NA % Extinguisher Media: This material does not support combustion. Use CO2, Dry Chemical, Foam Extinguisher or water spray. Do not use solid water streams. Phosphoric Acid reacts violently with water and can splatter personnel. Special Fire Fighting Procedures: Firefighters should wear NIOSH approved self-contained acid suits Unusual Fire and Explosion Hazards: Phosphorus oxide gas can be driven off of solutions SECTION VII PRECAUTIONS FOR SAFE HANDLING AND USE Precautions To Be Taken In Handling and Storage: Keep product from freezing. If frozen, thaw & agitate before use. Other Precautions: None Steps To Be Taken In Case Material Is Released Or Spilled: Large Spills: Dike and contain for intended use. Small Spills: Flush with water down the sewer Waste Disposal Method: Follow all Local, State, and Federal Regulations in your area. SECTION VIII OTHER REGULATORY INFORMATION SECTION 313 (With Chemicals Listed): This product contains the following toxic chemical(s) subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA) and 40 CFR Part 372: Ingredient CAS Number Weight Percent None NA NA SECTION IX SPECIAL PROTECTION & CONTROL MEASURES RESPIRATORY PROTECTION: None VENTILATION: Local Exhaust Mechanical Special Other xxx Protective Gloves: Rubber Eye Protection: Goggles Other Protective Clothing or Equipment: None Work/Hygiene Practices : Keep off of clothing SECTION X DOT SHIPPING INFORMATION DOT Shipping Name: Combustible liquid, n.o.s. (Contains Isopropyl Alcohol), 3, PG III, NA 1993 Label Requirements: NONE DOT Hazardous Substance CAS Number None NA Reportable Quantity (RQ) NA The information presented herein is based on data considered to be accurate as of the date of preparation of this Material Safety Data Sheet. However, no warranty or representation, expressed or implied, is made as to the accuracy or completeness of the foregoing data and safety information. In addition, no responsibility can be assumed by vendor for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices, or from any hazards inherent in the nature of the product. 3 Stability Conditions and Materials to Avoid Hazardous Decomposition or By -Products Polymerization Conditions to Avoid Inhalation Acute No known hazard Chronic Eye Contact Acute May cause stinging Chronic SECTION V REACTIVITY DATA Stable None known None None None known SECTION VI HEALTH HAZARD DATA Skin Contact Acute Long exposure to concentrated material will defat skin Chronic Ingestion Acute Can cause gastrointestinal irritation, nausea, vomiting, diarrhea, blindness, and death Chronic Medical Conditions Aggravated By Exposure None known Chemical Listed as Carcinogen or Potential Carcinogen No National Toxicology Program No I.A.R.C. Monographs: No OSHA: No ROUTES OF ENTRYIEMERGENCY AND FIRST AID PROCEDURES Inhalation Remove to fresh air Eyes: Rinse eyes with cool water for 15 minutes. Skin: Wash off with soap and water. Ingestion: Drink two glasses of water and induce vomiting. Never give anything to an unconscious person. Get medical attention. MATERIAL SAFETY DATA SHEET SECTION I SUPPLIER INFORMATION Common Name: Blue Wonder Shine Chemical Name: Formula: Supplier: Magic investments Inc. 427 Mount Lebanon Boulevard Pittsburgh, PA 15234 Phone: (412) 343 - 3555 Emergency Phone: Chem -Tel 1-800-255-3924 (24 hours) Date Prepared Monday, February 21, 2000 SECTION II HAZARDOUS INGREDIENT INFORMATION CFR 29 Part 1910.1000 Table Z-1 (July 1, 1995 issue) Ingredient CAS Number PEL-OSHA TWA -OSHA TLV-ACGIH STEL-ACGIH (ppm) (mg/m) (ppm) (ppm) . Isopropyl Alcohol 67-63-0 400 983 500 SECTION III PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: Specific Gravity: Melting Point: pH: Vapor Pressure (mm Hg): Vapor Density (Air— l ): Evaporation Rate (Butyl Acetate =1): Solubility in Water: Appearance and Odor: Biodegradability: Flash Point: Auto -Ignition Temperature: LEL: UEL: Extinguisher Media: Special Fire Fighting Procedures: 212 of 0.979 N/A of 7.0 - 7.5 N/A N/A N/A 100% A dark blue liquid with an alcohol odor. 100% SECTION IV FIRE AND EXPLOSION HAZARD DATA Unusual Fire and Explosion Hazards: 110 of N/A of N/A % N/A % Combustible liquid, use CO2, Dry Chemical, Foam Extinguisher or water spray. Do not use a direct water stream. Fire-fighter should wear self-contained breathing apparatus and full protective clothing. Use water spray to cool nearby containers and structures exposed to fire. Extinguish all nearby sources of ignition. Vapors formed from this product are heavier than air and may travel along the surface to a distant sources of ignition and flashback.. SECTION V REACTIVITY DATA Stability Stable Conditions and Materials to Avoid None known Hazardous Decomposition or By -Products None Polymerization None Conditions to Avoid None known SECTION VI HEALTH HAZARD DATA Inhalation Acute No known hazard Chronic Eye Contact Acute May cause stinging Chronic Skin Contact Acute Long exposure to concentrated material will defat skin Chronic Ingestion Acute Can cause gastrointestinal irritation, nausea, vomiting, diarrhea, blindness, and death Chronic Medical Conditions Aggravated By Exposure None known Chemical Listed as Carcinogen or Potential Carcinogen No National Toxicology Program No I.A.R.C. Monographs: No OSHA: No ROUTES OF ENTRY/EMERGENCY AND FIRST AID PROCEDURES Inhalation Remove to fresh air Eyes: Rinse eyes with cool water for 15 minutes. Skin: Wash off with soap and water. Ingestion: Drink two glasses of water and induce vomiting. Never give anything to an unconscious person. Get medical attention. 2 MATERIAL SAFETY DATA SHED j. SECTION I SUPPLIER INFORMATION Common Name: Pink Wonder Wax Chemical Name: Formula: Supplier: Magic Investments Inc. 427 Mount Lebanon Boulevard Pittsburgh, PA 15234 Phone: (412) 343 - 3555 Emergency Phone: Chem -Tel 1-800-255-3924 (24 hours) Date Prepared Monday, February 21, 2000 SECTION II HAZARDOUS INGREDIENT INFORMATION CFR 29 Part 1910.1000 Table Z-1 (July 1, 1994 issue) Ingredient CAS Number PEL-OSHA TWA -OSHA TLV-ACGIH STEL-ACGIH (Ppm) (mg/m) (PPm) (PPm) Isopropyl Alcohol 67-63-0 400 983 500 SECTION III PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: 212 of Specific Gravity: 0.979 Melting Point: N/A of pH: 7.0 - 7.5 Vapor Pressure (mm Hg): N/A Vapor Density (Air-1): N/A Evaporation Rate (Butyl Acetate =1): N/A Solubility in Water: 100% Appearance and Odor: A pink liquid with an alcohol odor. Biodegradability: 100% SECTION IV FIRE AND EXPLOSION HAZARD DATA Flash Point: 110 of Auto -Ignition Temperature: N/A of LEL: N/A % UEL: N/A % Extinguisher Media: Combustible liquid, use COZ, Dry Chemical, Foam Extinguisher or water spray. Do not use a direct water stream. Special Fire Fighting Procedures: Fire-fighter should wear self-contained breathing apparatus and full protective clothing. Use water spray to cool nearby containers and structures exposed to fire. Unusual Fire and Explosion Hazards: Extinguish all nearby sources of ignition. Vapors formed from this product are heavier than air and may travel along the surface to a distant sources of ignition and flashback.. SECTION VII PRECAUTIONS FOR SAFE HANDLING AND USE Precautions To Be Taken In Handling and Storage: Keep product from freezing. If frozen, thaw & agitate before use. Other Precautions: None Steps To Be Taken In Case Material Is Released Or Spilled: Large Spills: Dike and contain for intended use. Small Spills: Flush with water down the sewer Waste Disposal Method: Follow all Local, State, and Federal Regulations in your area. SECTION VIII OTHER REGULATORY INFORMATION SECTION 313 (With Chemicals Listed): This product contains the following toxic chemical(s) subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA) and 40 CFR Part 372: Ingredient None CAS Number NA Weight Percent NA SECTION IX SPECIAL PROTECTION & CONTROL MEASURES RESPIRATORY PROTECTION: None VENTILATION: Local Exhaust Mechanical Special xxx Protective Gloves: Rubber Eye Protection: Goggles Other Protective Clothing or Equipment: None Work/Hygiene Practices: Keep off of clothing SECTION X DOT SHIPPING INFORMATION DOT Shipping Name: Combustible liquid, n.o.s. (Contains Isopropyl Alcohol), 3, PG III, NA 1993 Label Requirements: NONE DOT Hazardous Substance CAS Number None NA Reportable Quantity (RQ) NA Other The information presented herein is based on data considered to be accurate as of the date of preparation of this Material Safety Data Sheet. However, no warranty or representation, expressed or implied, is made as to the accuracy or completeness of the foregoing data and safety information. In addition, no responsibility can be assumed by vendor for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices, or from any hazards inherent in the nature of the product. 3 SECTION V REACTIVITY DATA Stability Stable Conditions and Materials to Avoid None known Hazardous Decomposition or By -Products None Polymerization None Conditions to Avoid None known SECTION VI HEALTH HAZARD DATA Inhalation Acute No known hazard Chronic Eye Contact Acute May cause stinging Chronic Skin Contact Acute Long exposure to concentrated material will defat skin Chronic Ingestion Acute Can cause gastrointestinal irritation, nausea, vomiting, diarrhea, blindness, and death Chronic Medical Conditions Aggravated By Exposure None known Chemical Listed as Carcinogen or Potential Carcinogen No National Toxicology Program No I.A.R.C. Monographs: No OSHA: No ROUTES OF ENTRY/EMERGENCY AND FIRST AID PROCEDURES Inhalation Remove to fresh air Eyes: Rinse eyes with cool water for 15 minutes. Skin: Wash off with soap and water. Ingestion: Drink two glasses of water and induce vomiting. Never give anything to an unconscious person. Get medical attention. 0 MATERIAL SAFETY DATA SHEr;T SECTION I SUPPLIER INFORMATION Common Name: Yellow Wonder Shine (2x) Chemical Name: Formula: Supplier: Magic Investments Inc. 427 Mount Lebanon Boulevard Pittsburgh, PA 15234 Phone: (412) 343 — 3555 Emergency Phone: Chem -Tel 1-800-255-3924 (24 hours) Date Prepared Monday, February 21, 2000 SECTION Il HAZARDOUS INGREDIENT INFORMATION CFR 29 Part 1910.1000 Table Z-1 (July 1, 1998 issue) Ingredient CAS Number PEL-OSHA TWA -OSHA TLV-ACGIH STEL-ACGIH (PPm) (ml/m3) (ppm) (PPm) Isopropyl Alcohol 67-63-0 400 983 500 SECTION III PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: Specific Gravity: Melting Point: pH: Vapor Pressure (min Hg): Vapor Density (Air-1): Evaporation Rate (Butyl Acetate =1): Solubility in Water: Appearance and Odor: Biodegradability: Flash Point: Auto -Ignition Temperature: LEL: UEL: Extinguisher Media: Special Fire Fighting Procedures: 212 of 0.979 N/A of 7.0 - 7.5 N/A N/A N/A 100% A dark yellow liquid with an alcohol odor. 100% SECTION IV FIRE AND EXPLOSION HAZARD DATA Unusual Fire and Explosion Hazards: 110 of N/A of N/A % N/A % Combustible liquid, use COZ, Dry Chemical, Foam Extinguisher or water spray. Do not use a direct water stream. Fire-fighter should wear self-contained breathing apparatus and full protective clothing. Use water spray to cool nearby containers and structures exposed to fire. Extinguish all nearby sources of ignition. Vapors formed from this product are heavier than air and may travel along the surface to a distant sources of ignition and flashback.. SECTION VII PRECAUTIONS FOR SAFE HANDLING AND USE Precautions To Be Taken In Handling and Storage: Keep product from freezing. If frozen, thaw and agitate before use. Other Precautions: None Steps To Be Taken In Case Material Is Released Or Spilled: Large Spills: Dike and contain for intended use. Small Spills:DO NOT flush to sewers. Absorb on fire retardant treated sawdust, diatomaceous earth. Scrape up and remove. All clean-up and disposal should be carried out in accordance with federal, state, and local regulations. Waste Disposal Method: Incineration is the preferred method where permitted under appropriate federal, state, or local regulations. This product when spilled or disposed of is a non -hazardous solid waste as defined in Resource Conservation Recovery Act regulations. SECTION VIII OTHER REGULATORY INFORMATION SECTION 313 (With Chemicals Listed): This product contains the following toxic chemical(s) subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA) and 40 CFR Part 372: Ingredient None CAS Number NA Weight Percent NA SECTION IX SPECIAL PROTECTION & CONTROL MEASURES RESPIRATORY PROTECTION: U.S. Bureau of Mines Respirator; self contained breathing device, airline or NIOSH approved respirator. The specific respirator selected must be based on contamination levels in the work place, must be based on the specific operation, must not exceed the working limits of the respirator, and must be jointly approved by the National Institute of Occupational Safety and Health and the Mine Safety and Health Administration (NIOSH-MSHA). VENTILATION: Local Exhaust Mechanical xxx Protective Gloves: Rubber Eye Protection: Goggles Other Protective Clothing or Equipment: None Work/Hygiene Practices : Keep off of clothing Special Other SECTION V REACTIVITY DATA Stability Stable Conditions and Materials to Avoid Strong alkalies. High temperatures in the presence of strong bases. Acids. Strong oxidizing agents. Hazardous Decomposition or By -Products Carbon dioxide, carbon monoxide. Polymerization None Conditions to Avoid None known SECTION VI HEALTH HAZARD DATA Inhalation Acute High concentrations of vapor cause irritation to the respiratory tract, experienced as nasal discomfort and discharge, with chest pain and coughing. Headache, nausea, vomiting, dizziness, and drowsiness may occur. Chronic No data available Eye Contact Acute Causes severe irritation, experienced as discomfort or pain, excess blinking and tear production, with marked excess redness and swelling of the conjunctiva. Chronic No data available. Skin Contact Acute Brief contact may cause slight irritation with itching and local redness. Prolonged contact may cause more severe irritation, with discomfort or pain, local redness and swelling, and possible tissue destruction. Chronic No data available Ingestion Acute Moderately toxic. May cause headache, dizziness, incoordination, nausea, vomiting, diarrhea and general weakness. Ingestion of significant quantities may result in red blood cell hemolysis. Chronic No data available Medical Conditions Aggravated By Exposure Skin contact may aggravate an existing dermatitis Chemical Listed as Carcinogen or Potential Carcinogen No National Toxicology Program No I.A.R.C. Monographs: No OSHA: No ROUTES OF ENTRY/EMERGENCY AND FIRST AID PROCEDURES Inhalation Remove to fresh air Eyes: Rinse eyes with cool water for 15 minutes. Skin: Wash off with soap and water. Ingestion: If patient is fully conscious, gice two glasses of water. Induce vomiting. Obtain medical attention. 2 MATERIAL SAFETY DATA SHEh f SECTION I SUPPLIER INFORMATION Common Name: Magic Blend Tire White (10/17/97) Chemical Name: Formula: Supplier: Magic Investments Inc. 427 Mount Lebanon Boulevard Pittsburgh, PA 15234 Phone: (412) 343 - 3555 Emergency Phone: Chem -Tel 1-800-255-3924 (24 hours) Date Prepared Monday, February 21, 2000 SECTION II HAZARDOUS INGREDIENT INFORMATION CFR 29 Part 1910.1000 Table Z-1 (July 1, 1998 issue) Ingredient CAS Number PEL-OSHA TWA -OSHA TLV-ACGIH STEL-ACGIH (ppm) (ml/m) (PPm) (PPm) Monoehtanolamine 14143-5 3 7.5 (mg/in) 6 Ethylene Glycol Monobutyl Ether 111-76-2 25 121 25 SECTION III PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: 212 of Specific Gravity: 1.115 Melting Point: N/A of pH: 14 Vapor Pressure (mm Hg): N/A Vapor Density (Air-1): N/A Evaporation Rate (Butyl Acetate =1): N/A Solubility in Water: Complete Appearance and Odor: Clear yellow/green liquid, mild butyl odor. SECTION IV FIRE AND EXPLOSION HAZARD DATA Flash Point: none of Auto -Ignition Temperature: N/A of LEL: N/A % UEL: N/A % Extinguisher Media: Water, fog, alcohol foam, carbon dioxide and dry chemical. Do not use a direct water stream Special Fire Fighting Procedures: Shut off source off fuel, if possible and without risk. Keep personnel removed and upwind. Wear full protection clothing and self-contained breathing apparatus. Unusual Fire and Explosion Hazards: None known The information presented herein is based on data considered to be accurate as of the date of preparation of this Material Safety Data Sheet. However, no warranty or representation, expressed or implied, is made as to the accuracy or completeness of the foregoing data and safety information. In addition, no responsibility can be assumed by vendor for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices, or from any hazards inherent in the nature of the product. SECTION VII PRECAUTIONS FOR SAFE HANDLING AND USE Precautions To Be Taken In Handling and Storage: Store in a cool well -ventilated place, separated from all oxidizing materials. Other Precautions: Store away from incompatible substances. Steps To Be Taken In Case Material Is Released Or Spilled: Persons not wearing protective clothing must be restricted from area until clean up is complete. Dike flow of spilled material using soil or spill kits. Small amounts of acid may be flushed with large amounts of water. Large spills can be neutralized with Lime. Waste Disposal Method: Follow all Local, State and Federal Regulations in your area. SECTION VIII OTHER REGULATORY INFORMATION SECTION 313 (With Chemicals Listed): This product contains the following toxic chemical(s) subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA) and 40 CFR Part 372: Ingredient CAS Number Weight Percent Phosphoric Acid 7664-38-2 10 - 20 % SECTION IX SPECIAL PROTECTION & CONTROL MEASURES RESPIRATORY PROTECTION: U.S. Bureau of Mines Respirator; self-contained breathing device, airline or NIOSH approved respirator. The specific respirator selected must be based on contamination levels in the work place, must be based on the specific operation, must not exceed the working limits of the respirator, and must be jointly approved by the National Institute of Occupational Safety and Health and the Mine Safety and Health Administration (NIOSH-MSHA). VENTILATION: Local Exhaust Mechanical Special Other Xxx Protective Gloves: Heavy PVC gaunlet gloves Eye Protection: Splash -proof or dust resistant safety goggles and a faceshield to prevent contact with this substance. Other Protective Clothing or Equipment: Appropriate protective (impervious) clothing and equipment to prevent contact with this substance. Eyewashes and drench showers should be in the immediate work area. Work/Hygiene Practices: Keep off of clothing SECTION X DOT SHIPPING INFORMATION DOT Shipping Name: Compound cleaning liquid, n.o.s. (contains acetic acid, phosphoric acid) PG III, NA 1760 Label Requirements: CORROSIVE DOT Hazardous Substance CAS Number Reportable Quantity (RQ) Phosphoric Acid 7664-38-2 5000 lbs. Acetic Acid 64-19-7 5000 lbs. SECTION V REACTIVITY DATA Stability Stable Conditions and Materials to Avoid Alkalis, oxidizers, and most metals Hazardous Decomposition or By -Products Thermal decomposition may release corrosive phosphoric oxide fumes and acid mist. Polymerization Will not occur Conditions to Avoid None known SECTION VI HEALTH HAZARD DATA Inhalation Acute CORROSIVE: Inhalation may cause choking, coughing, and irritation of the throat. Ulceration of the nose, throat, or larynx, bronchitis, pneumonia, palpitations, and headache. Chronic Repeated or prolonged exposure may cause erosion and discoloration of exposed teeth, chronic bronchitis and gastritis. Eye Contact Acute CORROSIVE: Contact may cause severe irritation, conjunctivitis, corneal necrosis and bums with impairment or permanent loss of vision. Clouding or corrosion of the cornea. Chronic Effects are dependent on concentration and duration. See acute exposure. Skin contact Acute CORROSIVE: Contact may cause severe irritation, inflammation, ulceration, necrosis, and chemical bums. Chronic Repeated or prolonged contact with vapors or dilute solutions may cause dermatitis or slow healing chemical burns. Photosensitization may occur. Ingestion Acute CORROSIVE: May cause bums of the mouth, throat, esophagus and stomach with consequent pain, uneasiness nausea, salivation, vomiting, diarrhea, chills, shock and intense thirst. Chronic No data available Medical Conditions Aggravated By Exposure None known Chemical Listed as Carcinogen or Potential Carcinogen No National Toxicology Program I.A.R.C. Monographs: NO OSHA: NO ROUTES OF ENTRY/EMERGENCY AND FIRST AID PROCEDURES Inhalation Remove to fresh air. If breathing has stopped, give artificial respiration. Get medical attention. Even in the absence of symptoms, a worker must not be permitted to return to work for at least 24 hours. Eyes: Rinse eyes with large amounts of cool water for 15-20 minutes lifting upper and lower lids. Rinse with saline solution until the pH is back to normal (30-60 minutes) Get Medical Attention preferably an eye specialist. Skin: Remove contaminated clothing. Wash off with soap and large amounts of water. Use a good skin emollient. If skin is burned, cover with a sterile dry dressing and seek Medical Attention. Ingestion: Do not use gastric lavage or emesis. Dilute acid immediately by drinking large amounts of water or milk. Ingested acid must be diluted 100 fold to render it harmless. Get Medical Attention. F] MATERIAL SAFETY DATA SHEET SECTION I SUPPLIER INFORMATION Common Name: Magic Blend Special Foam Soap Chemical Name: Formula: Supplier: Magic Investments Inc. 427 Mount Lebanon Boulevard Pittsburgh, PA 15234 Phone: (412) 343 — 3555 Emergency Phone: Chem -Tel 1-800-255-3924 (24 hours) Date Prepared: Monday, February 21, 2000 SECTION II HAZARDOUS INGREDIENT INFORMATION CFR 29 Part 19 10. 1000 Table Z-1 (July 1, 1998 issue) Ingredient CAS Number PEL-OSHA TWA -OSHA TLV-ACGIH STEL-ACGIH (ppm) (mg m3) (ppm) (ppm) Acetic Acid 64-19-7 10 25 10 15 Phosphoric Acid 7664-38-2 1 (mg/in) 1 1 (mg/m) 3 (mg/in) SECTION III PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: Specific Gravity: Melting Point: pH: Vapor Pressure (min Hg): Vapor Density (Air-1): Evaporation Rate (Butyl Acetate =1): Solubility in Water: Appearance and Odor: Flash Point: Auto -Ignition Temperature: LEL: UEL: Extinguisher Media: Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: 212 of 1.04 N/A of <1 N/A N/A N/A 100% A clear liquid with a strong vinegar odor. SECTION IV FIRE AND EXPLOSION HAZARD DATA None of None of NA % NA % This material does not support combustion. Use COz, Dry Chemical, Foam Extinguisher or water spray. Do not use solid water streams. Phosphoric Acid reacts violently with water and can splatter personnel. Firefighters should wear NIOSH approved self-contained acid suits Phosphorus oxide gas can be driven off of solutions SECTION X DOT SHIPPING INFORMATION DOT Shipping Name: Toxic, liquids organic, n.o.s. (Contains Ethylene Glycol Monobutyl Ether), 6.1, PG III, UN - 2810 Label Requirements: KEEP AWAY FROM FOOD DOT Hazardous Substance CAS Number None NA Reportable Quantity (RQ) NA The information presented herein is based on data considered to be accurate as of the date of preparation of this Material Safety Data Sheet. However, no warranty or representation, expressed or implied, is made as to the accuracy or completeness of the foregoing data and safety information. In addition, no responsibility can be assumed by vendor for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices, or from any hazards inherent in the nature of the product. SECTION VII PRECAUTIONS FOR SAFE HANDLING AND USE Precautions To Be Taken In Handling and Storage: Keep product from freezing. If frozen, thaw and agitate before use. Other Precautions : None Steps To Be Taken In Case Material Is Released Or Spilled: Large Spills: Dike and contain for intended use. Small Spills:DO NOT flush to sewers. Absorb on fire retardant treated sawdust, diatomaceous earth. Scrape up and remove. All clean-up and disposal should be carried out in accordance with federal, state, and local regulations. Waste Disposal Method: Incineration is the preferred method where permitted under appropriate federal, state, or local regulations. This product when spilled or disposed of is a non -hazardous solid waste as defined in Resource Conservation Recovery Act regulations. SECTION VIII OTHER REGULATORY INFORMATION SECTION 313 (With Chemicals Listed): This product contains the following toxic chemical(s) subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA) and 40 CFR Part 372: Ingredient CAS Number Weight Percent None NA NA SECTION IX SPECIAL PROTECTION & CONTROL MEASURES RESPIRATORY PROTECTION: U.S. Bureau of Mines Respirator; self contained breathing device, airline or NIOSH approved respirator. The specific respirator selected must be based on contamination levels in the work place, must be based on the specific operation, must not exceed the working limits of the respirator, and must be jointly approved by the National Institute of Occupational Safety and Health and the Mine Safety and Health Administration (NIOSH-MSHA). VENTILATION: Local Exhaust Mechanical Special Other xxx Protective Gloves: Rubber Eye Protection: Goggles Other Protective Clothing or Equipment: None Work/Hygiene Practices: Keep off of clothing Stability Conditions and Materials to Avoid Hazardous Decomposition or By -Products Polymerization Conditions to Avoid SECTION V REACTIVITY DATA Stable Strong alkalies. High temperatures in the presence of strong bases. Acids. Strong oxidizing agents. Carbon dioxide, carbon monoxide. None None known SECTION VI HEALTH HAZARD DATA Inhalation Acute High concentrations of vapor cause irritation to the respiratory tract, experienced as nasal discomfort and discharge, with chest pain and coughing. Headache, nausea, vomiting, dizziness, and drowsiness may occur. Chronic No data available Eye Contact Acute Causes severe irritation, experienced as discomfort or pain, excess blinking and tear production, with marked excess redness and swelling of the conjunctiva. Chronic No data available. Skin Contact Acute Brief contact may cause slight irritation with itching and local redness. Prolonged contact may cause more severe irritation, with discomfort or pain, local redness and swelling, and possible tissue destruction. Chronic No data available Ingestion Acute Moderately toxic. May cause headache, dizziness, incoordination, nausea, vomiting, diarrhea and general weakness. Ingestion of significant quantities may result in red blood cell hemolysis. Chronic No data available Medical Conditions Aggravated By Exposure Skin contact may aggravate an existing dermatitis Chemical Listed as Carcinogen or Potential Carcinogen No National Toxicology Program No I.A.R.C. Monographs: No OSHA: No ROUTES OF ENTRY/EMERGENCY AND FIRST AID PROCEDURES Inhalation Remove to fresh air Eyes: Rinse eyes with cool water for 15 minutes. Skin: Wash off with soap and water. Ingestion: If patient is fully conscious, gice two glasses of water. Induce vomiting. Obtain medical attention. 2 IVIATERIAL SAFETY DATA SHEL r SECTION I SUPPLIER INFORMATION Common Name: Magic Wash Away Prep Gun Soap Chemical Name: Formula: Supplier: Magic Investments Inc. 427 Mount Lebanon Boulevard Pittsburgh, PA 15234 Phone: (412) 343 - 3555 Emergency Phone: Chem -Tel 1-800-255-3924 (24 hours) Date Prepared Monday, February 21, 2000 SECTION II HAZARDOUS INGREDIENT INFORMATION CFR 29 Part 1910.1000 Table Z-1 (July 1, 1998 issue) Ingredient CAS Number PEL-OSHA TWA -OSHA TLV-ACGIH STEL-ACGIH (ppm) (mg m3) (ppm) (ppm) Ethylene Glycol Monobutyl Ether 111-76-2 25 121 25 SECTION III PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: 212 of Specific Gravity: 1.02 Melting Point: N/A of pH: 13 Vapor Pressure (mm Hg): N/A Vapor Density (Air--1): N/A Evaporation Rate (Butyl Acetate =1): N/A Solubility in Water: Complete Appearance and Odor: Clear liquid, mild odor. SECTION IV FIRE AND EXPLOSION HAZARD DATA Flash Point: none of Auto -Ignition Temperature: N/A of LEL: N/A % UEL: N/A % Extinguisher Media: Water, fog, alcohol foam, carbon dioxide and dry chemical. Do not use a direct water stream Special Fire Fighting Procedures: Shut off source off fuel, if possible and without risk. Keep personnel removed and upwind. Wear full protection clothing and self-contained breathing apparatus. Unusual Fire and Explosion Hazards: None known • Health hazards, including signs and symptoms of exposure associated with exposure to chemicals and any medical condition known to be aggravated by exposure to the chemical. • Procedures to protect against hazards (e.g. personal protective equipment required, proper use and maintenance; work practices or methods to assure proper use and handling of chemicals; and procedures for emergency response). • Work procedures to follow to assure protection when cleaning hazardous chemical spills and leaks. • Where MSDS's are located, how to read and interpret the information on both labels and MSDS's and how employees may obtain additional information. James R. Frank will review the employee training program and meet the retraining needs. Retraining is required when the hazard changes or when a new hazard is introduced into the workplace, but it will be the company policy to provide retraining at least annually for all employees to ensure the effectiveness of the program. Also, new employees will be trained as they come on board. James R. Frank will obtain input from employees regarding the training they have received, and their suggestions for improving it. Additional Information All employees can obtain further information on this written program, the hazard communication standard, applicable MSDS's, and chemical information lists from James R. Frank at Richie's Express Carwash. Labels and Other Forms of Warning James R. Frank will ensure that all hazardous chemicals in the workplace are properly labeled and updated as necessary. Labels should list at least the chemical identity, appropriate hazard warnings and the name and address of the manufacturer, importer or other responsible party. James R. Frank will refer to the corresponding MSDS to assist you in verifying label information. Containers that are shipped from the workplace will be checked by James R Frank to make sure all containers are properly labeled. If there are a number of stationary containers within a work area that have similar contents and hazards, signs will be posted on them to convey the hazard information. On our stationary process equipment, regular process sheets, batch tickets, blend tickets, and similar written materials will be substituted for container labels when they contain the same information as labels. These written materials will be made readily available to you during your work shift at each work site as appropriate. If you transfer chemicals from a labeled container to a portable container that is intended only for your immediate use, no labels are required on the portable container. Pipes or piping systems will not be labeled but their contents will be described in the training sessions. Remember, do not use products which are unlabeled or with defaced labels and report such incidences to James R. Frank. Non -Routine Tasks When you are required to perform hazardous non -routine tasks, a special training session will be conducted to inform you regarding the hazardous chemicals to which you might be exposed and the proper precautions to take to reduce or avoid exposure. Training Everyone who works with or is potentially exposed to hazardous chemicals will receive initial training on the Hazard Communication Standard and the safe use of those hazardous chemicals by James R. Frank. A program has been prepared for this purpose. Whenever a new hazard is introduced, additional training will be provided. At least yearly, review of the program will take place. James R. Frank will be available to answer any questions from workers on the program or the products in use. The training program will emphasize these items: • Summary of the standard and this written program. • Chemical and physical properties of hazardous materials (e.g. flash point, reactivity) and methods that can be used to detect the presence or release of chemicals (including chemicals in unlabeled pipes). 0 Physical hazards of chemicals (e.g. potential for fire, explosion, etc.) RICHIE'S EXPRESS CARWASH HAZARD COMMUNICATION PROGRAM General Company PolicX The purpose of this notice is to inform you that our company is complying with the PSHA Hazard Communication Standard. Title 29 CFR 1910.1200, by compiling a hazardous chemicals list, by using MSDS's, by ensuring that containers are labeled, and by providing you with training. This program applies to all work operations in our company where you may be exposed to hazardous substances under normal working conditions or during an emergency situation. James R. Frank is the program coordinator and has overall responsibility for the program. James R. Frank will review and update the program as necessary. Copies of the written program may be obtained from James R. Frank or Richie's Express Carwash. Under this program, you will be informed of the contents of the Hazard Communication Standard, the hazardous properties of chemicals with which you work, safe handling, procedure, and measures to take to protect yourself from these chemicals. You will also be informed of the hazards associated with non -routine tasks, and the hazards associated with chemicals in unlabeled pipes List of Hazardous Chemicals James R. Frank will make a list of all hazardous chemicals and related work practices used at this location and will update the list as necessary. Our list of chemicals identifies all of the chemicals used in our work processes. Each list also identifies the corresponding MSDS for each chemical. A master list of these chemicals will be maintained by James R. Frank and is located in Richie's Express Carwash. Materials Safety Data Sheets (MSDS's) MSDS's provide you with specific information on the chemicals you use. James R. Frank will maintain a binder with an MSDS on every substance on the list of hazardous chemicals. The MSDS will be a fully completed OSHA form 174 or equivalent. James R. Frank will ensure that each work site maintains an MSDS for hazardous materials in that area. MSDS's will be readily available to you during your work shifts. James R. Frank is responsible for acquiring and updating MSDS's. He will contact the chemical manufacturer or vendor if additional research is necessary or if an MSDS has not been supplied with an initial shipment. James R. Frank must clear all procurements for the company. Do not use a product that has no MSDS.