HomeMy WebLinkAboutNEW BELGIUM, 4TH FILING, PACKAGING HALL & BUCKINGHAM ST. - PDP & AMENDED ODP - 1-95F - SUBMITTAL DOCUMENTS - ROUND 1 - HAZMATSAppearance: Thin liquid Odor: Mild
Vapor Pressure: 19.8 mm Hg Vapor Density: 958.8
Evaporation Rate (BuOac=1): 0.33 Boiling Point: > 212 deg F
Solubility in Water: Complete Specific Gravity: 1.066
Melting Point: <32 deg F pH: 0.7
SECTION 10 - STABILITY AND REACTIVITY
Chemical Stability: Stable.
Conditions to Avoid: Avoid extremes in temperature.
Incompatibility (Materials to avoid): Strong reducers, Alkalies
Hazardous Decomposition or Byproducts: None.
Hazardous Polymerization: Will not occur.
SECTION 11 - TOXICOLOGY INFORMATION
To obtain toxicity data (e.g., LD50, LC50) for the ingredients listed in Section 2, please phone Technical Services at
(800) 554-8265.
SECTION 12 - ECOLOGICAL INFORMATION
9388 is fully biodegradable. To obtain specific ecotoxicity or environmental fate data, please phone Technical Services
at (800) 554-8265.
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal Method: Dispose of in accordance with all applicable local, state, county and federal laws.
SECTION 14 - TRANSPORT INFORMATION
Shipping Name: Compound, Cleaning, Liquid, (Phosphoric Acid)
Hazard Class: 8 ID No.: NA 1760 Packing Group: III
SECTION 15 - REGULATORY INFORMATION
All ingredients in 9388 are listed on the TSCA inventory.
SECTION 16 - OTHER INFORMATION
CHEMSTATION HAZARD IDENTIFICATION:
Health: 2 Flammability: 0 Reactivity: 0
The data in this material safety data sheet relates only to the specific material designated herein and does not relate to use in combination
with any other material or in any process. This information is based upon technical data we believe is reliable. Because actual conditions
of use are outside our control, no warranties, expressed or implied, are made and we assume no liability in connection with any use of
this information.
Every effort has been made to accurately assess the possible hazards associated with this product. We believe that the actual hazards
encountered using our products are less severe than those represented by the concentrated raw materials used to make them.
Ivlm I Gnlp%L. JMI G VF11 PA %71 IGG I
Product Name: 9388
Manufacturer's Name: ChemStation Denver, LLC
Address: 4800 Lima St
Denver, CO, 80239
Telephone Number: (303) 288-8500
Emergency Telephone Number: CHEMTREC (800) 424-9300
Date Prepared: March 25, 2004
SECTION 2 - COMPOSITION
Chemical Name:
citric acid
phosphoric acid
proprietary surfactant blend
water
This product contains no OSHA, NTP, or IARC listed
CAS No.:
TLV:
%:
77-92-9
none
0-5
7664-38-2
1.000 ppm
10-15
none
none
0-5
7732-18-5
none
q.s.
SECTION 3 - HAZARDS IDENTIFICATION
Emergency Overview: Thin liquid which is corrosive.
Eyes: Corrosive.
Skin: Corrosive
Inhalation (respiratory tract): Corrosive.
Ingestion (gastrointestinal tract): Corrosive.
Chronic (Cancer) Effects: Components of material do not cause cancer.
Teratology (Birth Defect) Information: Components do not cause birth defects.
SECTION 4 - FIRST AID MEASURES
Eyes: Flush immediately with running water for fifteen minutes. See a physician.
Skin: Flush with water. See a physician if necessary.
Inhalation (respiratory tract): Remove to fresh air. See a physician if necessary.
Ingestion (gastrointestinal tract): Dilute stomach contents with water, if conscious. See a physician.
SECTION 5 - FIRE FIGHTING MEASURES
Flash Point: >200 deg F (non-flammable)
Flammable Limits: None
Autoignition Temperature: None
Extinguishing Media: Product is non-combustible. Water, foam, carbon dioxide or dry chemical may be used.
Special Fire Fighting Procedures: Standard fire fighting procedures apply.
Unusual Fire and Explosion Hazards: No unusual fire hazards.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Action to Take for Spills and Leaks: Small spills should be mopped up. Large spills should be diked with inert ab-
sorbent. Material may be pumped back into container or neutralized for disposal.
SECTION 7 - HANDLING AND STORAGE
Handling: Avoid contact with eyes. Avoid prolonged contact with skin. Do not ingest. Keep out of reach of children.
Storage: Store product in ambient temperature. Avoid freezing or high heat.
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
Personal Protective Equipment:
Eye Protection: Safety Eyewear
Skin Protection: Latex, natural rubber, neoprene or nitrile gloves are recommended.
Respiratory Protection: Not normally required. If needed, such as in enclosed areas, use NIOSH-approved mask or res-
pirator to keep concentrations of components below their TLV's.
Other Protective Clothing or Equipment:
Ventilation: Normal room air circulation.
For exposure control levels such as Threshold Limit Values (TLV's) please refer to Section 2.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Thin liquid Odor: Mild
Vapor Pressure: Not Determined Vapor Density: Not Determined
Evaporation Rate (Bu0ac=1): 0.33 Boiling Point: > 212 deg F
Solubility in Water: Complete Specific Gravity: 1.026
Melting Point: <32 deg F pH: 12.6
SECTION 10 - STABILITY AND REACTIVITY
Chemical Stability: Stable.
Conditions to Avoid: Avoid extremes in temperature.
Incompatibility (Materials to avoid): Strong oxidizers, acids.
Hazardous Decomposition or Byproducts: None.
Hazardous Polymerization: Will not occur.
SECTION 11 - TOXICOLOGY INFORMATION
To obtain toxicity data (e.g., LD50, LC50) for the ingredients listed in Section 2, please phone Technical Services at
(800)554-8265.
SECTION 12 - ECOLOGICAL INFORMATION
3902 is fully biodegradable. To obtain specific ecotoxicity or environmental fate data, please phone Technical Services
at (800) 554-8265.
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal Method: Dispose of in accordance with all applicable local, state, county and federal laws.
SECTION 14 - TRANSPORT INFORMATION
Shipping Name: Compound, Cleaning, N.O. I., Liquid
Hazard Class: None ID No.: None Packing Group: None
SECTION 16 - REGULATORY INFORMATION
All ingredients in 3902 are listed on the TSCA inventory.
SECTION 16 - OTHER INFORMATION
CHEMSTATION HAZARD IDENTIFICATION:
Health: 1 Flammability: 0 Reactivity: 0
The data in this material safety data sheet relates only to the specific material designated herein and does not relate to use in combination
with any other material or in any process. This information is based upon technical data we believe is reliable. Because actual conditions
of use are outside our control, no warranties, expressed or implied, are made and we assume no liability in connection with any use of
this information.
Every effort has been made to accurately assess the possible hazards associated with this product. We believe that the actual hazards
encountered using our products are less severe than those represented by the concentrated raw materials used to make them.
Product: 3902 Date Prepared: September 08, 2004 Page 2
MATERIAL SAFETY DATA SHEET
Product Name: 3902
Manufacturer's Name: ChemStation International, Inc.
Address: 3400 Encrete Lane
Dayton, OH, 45439
Telephone Number: (800) 554-8265
Emergency Telephone Number: CHEMTREC (800) 424-9300
Date Prepared: September 08, 2004
SECTION 2 - COMPOSITION
Chemical Name:
CAS No.: TLV: %:
proprietary surfactant blend
none none 0-5
water
7732-18-5 none q.s.
This product contains no OSHA,
NTP, or IARC listed carcinogens.
SECTION 3 - HAZARDS IDENTIFICATION
Emergency Overview: Thin liquid which is irritating.
Eyes: Irritating.
Skin: Irritating
Inhalation (respiratory tract): Irritating.
Ingestion (gastrointestinal tract): Irritating.
Chronic (Cancer) Effects: Components of material do not cause cancer.
Teratology (Birth Defect) Information: Components do not cause birth defects.
SECTION 4 - FIRST AID MEASURES
Eyes: Flush immediately with running water for fifteen minutes. See a physician.
Skin: Flush with water. See a physician if necessary. I .
Inhalation (respiratory tract): Remove to fresh air. See a physician if necessary.
Ingestion (gastrointestinal tract): Dilute stomach contents with water, if conscious. See a physician. -
SECTION 5 - FIRE FIGHTING MEASURES
Flash Point: >200 degrees F (non-flammable)
Flammable Limits None
Autoignition Temperature: None
Extinguishing Media: Product is non-combustible. Water, foam, carbon dioxide or dry chemical may be used.
Special Fire Fighting Procedures: Standard fire fighting procedures apply.
Unusual Fire and Explosion Hazards: No unusual fire hazards.
SECTION 6 -ACCIDENTAL RELEASE MEASURES
Action to Take for Spills and Leaks: Small spills should be mopped up. Large spills should be diked with inert ab-
sorbent. Material may be pumped back into container or neutralized for disposal.
SECTION 7 - HANDLING AND STORAGE
Handling: Avoid contact with eyes. Avoid prolonged contact with skin. Do not ingest. Keep out of reach of children.
Storage: Store product in ambient temperature. Avoid freezing or high heat.
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
Personal Protective Equipment:
Eye Protection: Safety Eyewear
Skin Protection: Latex, natural rubber, neoprene or nitrile gloves are recommended.
Respiratory Protection: Not normally required. If needed, such as in enclosed areas, use NIOSH-approved mask or res-
pirator to keep concentrations of components below their TLV's.
Other Protective Clothing or Equipment:
Ventilation: Normal room air circulation.
For exposure control levels such as Threshold Limit Values (TLV's) please refer to Section 2.
Product: 3902 Date Prepared: September 08, 2004 Page 1
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Appearance: White Emulsion Odor: Mild
Vapor Pressure: Not Determined Vapor Density: Not Determined
Evaporation Rate (Bu0ac=1): 0.33 Boiling Point: > 212 deg F
Solubility in Water: Complete Specific Gravity: 1.026
Melting Point: <32 deg F pH: 9.2
SECTION 10 - STABILITY AND REACTIVITY
Chemical Stability: Stable.
Conditions to Avoid: Avoid extremes in temperature.
Incompatibility (Materials to avoid): Strong oxidizers, acids.
Hazardous Decomposition or Byproducts: None.
Hazardous Polymerization: Will not occur.
SECTION 11 - TOXICOLOGY INFORMATION
To obtain toxicity data (e.g., LD50, LC50) for the ingredients listed in Section 2, please phone Technical Services at
(800)554-8265.
SECTION 12 - ECOLOGICAL INFORMATION
3691 is fully biodegradable. To obtain specific ecotoxicity or environmental fate data, please phone Technical Services
at (800) 554-8265.
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal Method: Dispose of in accordance with all applicable local, state, county and.federal laws.
SECTION 14 - TRANSPORT INFORMATION
Shipping Name: Compound, Cleaning,N.O.I., Liquid
Hazard Class: None ID No.: None Packing Group: None
SECTION 15 - REGULATORY INFORMATION
All ingredients in 3691 are listed on the TSCA inventory.
SECTION 16 -OTHER INFORMATION
CHEMSTATION HAZARD IDENTIFICATION:
Health: 1 Flammability: 0 Reactivity: 0
The data in this material safety data sheet relates only to the specific material designated herein and does not relate to use in combination
with any other material or in any process. This information is based upon technical data we believe is reliable. Because actual conditions
of use are outside our control, no warranties, expressed or implied, are made and we assume no liability in connection with any use of
this information.
Every effort has been made to accurately assess the possible hazards associated with this product. We believe that the actual hazards
encountered using our products are less severe than those represented by the concentrated raw materials used to make them.
Product: 3691 Date Prepared: March 25, 2004 Page 2
MATERIAL SAFETY DATA SHEET
Product Name: 3691
Manufacturer's Name: ChemStation Denver, LLC
Address: 4800 Lima St
Denver, CO, 80239
Telephone Number: (303) 288-8500
Emergency Telephone Number: CHEMTREC (800) 424-9300
Date Prepared: March 25, 2004
SECTION 2 - COMPOSITION
Chemical Name: CAS No.: TLV: %:
diethanolamine oleate 13961-86-9 none 0-5
polyethylene glycol oleyl ether phosphate 39464-69-2 none 0-5
water 7732-18-5 none q.s.
This product contains no OSHA, NTP, or IARC listed carcinogens.
SECTION 3 - HAZARDS IDENTIFICATION
Emergency Overview: White Emulsion which is irritating.
Eyes: Irritating.
Skin: Irritating
Inhalation (respiratory tract): Irritating.
Ingestion (gastrointestinal tract): Irritating.
Chronic (Cancer) Effects: Components of material do not cause cancer.
Teratology (Birth Defect) Information: Components do not cause birth defects.
SECTION 4 - FIRST AID MEASURES
Eyes: Flush immediately with running water for fifteen minutes. See a physician.
Skin: Flush with water. See a physician if necessary.
Inhalation (respiratory tract): Remove to fresh air. See a physician if necessary.
Ingestion (gastrointestinal tract): Dilute stomach contents with water, if conscious. See a physician.
SECTION 5 - FIRE FIGHTING MEASURES
Flash Point: >200 deg F (non-flammable)
Flammable Limits: None
Autoignition Temperature: None
Extinguishing Media: Product is non-combustible. Water, foam, carbon dioxide or dry chemical may be used.
Special Fire Fighting Procedures: Standard fire fighting procedures apply.
Unusual Fire and Explosion Hazards: No unusual fire hazards.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Action to Take for Spills and Leaks: Small spills should be mopped up. Large spills should be diked with inert ab-
sorbent. Material may be pumped back into container or neutralized for disposal.
SECTION 7 - HANDLING AND STORAGE
Handling: Avoid contact with eyes. Avoid prolonged contact with skin. Do not ingest. Keep out of reach of children.
Storage: Store product in ambient temperature. Avoid freezing or high heat.
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
Personal Protective Equipment:
Eye Protection: Safety Eyewear
Skin Protection: Latex, natural rubber, neoprene or nitrile gloves are recommended.
Respiratory Protection: Not normally required. If needed, such as in enclosed areas, use NIOSH-approved mask or res-
pirator to keep concentrations of components below their TLV's.
Other Protective Clothing or Equipment:
Ventilation: Normal room air circulation.
For exposure control levels such as Threshold Limit Values (TLV's) please refer to Section 2.
Product: 3691 Date Prepared: March 25, 2004 Page 1
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Thin liquid Odor: Mild
Vapor Pressure: Not Determined Vapor Density: Not Determined
Evaporation Rate (BuOac=1): 0.33 Boiling Point: > 212 deg F
Solubility in Water: Complete Specific Gravity: 1.134
Melting Point: <32 deg F pH: 14.0
SECTION 10 - STABILITY AND REACTIVITY
Chemical Stability: Stable.
Conditions to Avoid: Avoid extremes in temperature.
Incompatibility (Materials to avoid): Ammonia, amines, strong oxidizers, acids.
Hazardous Decomposition or Byproducts: May release chlorine gas.
Hazardous Polymerization: Will not occur.
SECTION 11 -TOXICOLOGY INFORMATION
To obtain toxicity data (e.g., LD50, LC50) for the ingredients listed in Section 2, please phone Technical Services at
(800) 554-8265.
SECTION 12 - ECOLOGICAL INFORMATION
3205 is fully biodegradable. To obtain specific ecotoxicity or environmental fate data, please phone Technical Services
at (800) 554-8265.
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal Method: Dispose of in accordance with all applicable local, state, county and federal laws.
SECTION 14 - TRANSPORT INFORMATION
Shipping Name: Compound, Cleaning, Liquid, (Potassium Hydroxide)
Hazard Class: 8 ID No.: NA 1760 Packing Group: III
SECTION 15 - REGULATORY INFORMATION
All ingredients in 3205 are listed on the TSCA inventory.
SECTION 16 -OTHER INFORMATION
CHEMSTATION HAZARD IDENTIFICATION:
Health: 2 Flammability: 0 Reactivity: 1
The data in this material safety data sheet relates only to the specific material designated herein and does not relate to use in combination
with any other material or in any process. This information is based upon technical data we believe is reliable. Because actual conditions
of use are outside our control, no warranties, expressed or implied, are made and we assume no liability in connection with any use of
this information.
Every effort has been made to accurately assess the possible hazards associated with this product. We believe that the actual hazards
encountered using our products are less severe than those represented by the concentrated raw materials used to make them.
Product: 3205 Date Prepared: February 02, 2004 Page 2
MATERIAL SAFETY DATA SHEET
Product Name: 3205
Manufacturer's Name: ChemStation Denver, LLC
Address: 4800 Lima St
Denver, CO, 80239
Telephone Number: (303) 288-8500
Emergency Telephone Number: CHEMTREC (800) 424-9300
Date Prepared: February 02, 2004
SECTION 2 - COMPOSITION
Chemical Name: CAS No.: TLV: %:
potassium hydroxide 1310-58-3 2.000 ppm 5-10
sodium hydroxide 1310-73-2 2.000 ppm 0-5
sodium hypochlorite 7681-52-9 none 0-5
water 7732-18-5 none q.s.
This product contains no OSHA, NTP, or IARC listed carcinogens.
SECTION 3 - HAZARDS IDENTIFICATION
Emergency Overview: Thin liquid which is corrosive.
Eyes: Corrosive.
Skin: Corrosive
Inhalation (respiratory tract): Corrosive.
Ingestion (gastrointestinal tract): Corrosive.
Chronic (Cancer) Effects: Components of material do not cause cancer.
Teratology (Birth Defect) Information: Components do not cause birth defects.
SECTION 4 - FIRST AID MEASURES
Eyes: Flush immediately with running water for fifteen minutes. See a physician.
Skin: Flush with water. See a physician if necessary.
Inhalation (respiratory tract): Remove to fresh air. See a physician if necessary.
Ingestion (gastrointestinal tract): Dilute stomach contents with water, if conscious. See a physician.
SECTION 5 - FIRE FIGHTING MEASURES
Flash Point: >200 deg F (non-flammable)
Flammable Limits: None
Autoignition Temperature: None
Extinguishing Media: Foam, carbon dioxide or dry chemical.
Special Fire Fighting Procedures: Product is fragrant. Respirators should be used to fight fire on concentrated product
while no respirator is needed on diluted material.
Unusual Fire and Explosion Hazards: Contact with aluminum and other soft metals can generate flammable hydrogen
gas.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Action to Take for Spills and Leaks: Small spills should be mopped up. Large spills should be diked with inert ab-
sorbent. Material may be pumped back into container or neutralized for disposal.
SECTION 7 - HANDLING AND STORAGE
Handling: Avoid contact with eyes. Avoid prolonged contact with skin. Do not ingest. Keep out of reach of children.
Storage: Store product in ambient temperature. Avoid freezing or high heat.
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
Personal Protective Equipment:
Eye Protection: Safety Eyewear
Skin Protection: Latex, natural rubber, neoprene or nitrile gloves are recommended.
Respiratory Protection: Not normally required. If needed, such as in enclosed areas, use NIOSH-approved mask or res-
pirator to keep concentrations of components below their TLV's.
Other Protective Clothing or Equipment:
Ventilation: Normal room air circulation.
For exposure control levels such as Threshold Limit Values (TLV's) please refer to Section 2.
Product: 3205 Date Prepared: February 02, 2004 Page 1
REVISION SUMMARY Revisilon #: 3;
This MSDS replaces the February 09, 1998 MSDS. Any changes in information are as follows:
In Section 15
Regulatory Information
IOIrI�u1P�G�al11Y11•� ► i�w:�►•�n�►:�a:�rr•���
ivary�x�r�cnc�� ���xy►:��t��
Key
4 = Severe
3 = Serious
2 = Moderate
1 = Slight
0 = Minimal
HMIS RATINGS NOTES: Protection = H (Safety goggles, gloves, apron and a vapor
respirator)
The contents and format of this MSDS are in accordance with OSHA Hazard Communication Standard
and Canada's Workplace Hazardous information System (WHMIS).
Section(s) Revised : New Format
National Fire Protection Association (NFPA)
SPECIAL = OX (Oxidizer)
Hazardous Materials Identification System (HMIS)
http://msds.princeton.fmc.com/msds/2477hi l j'.htm 06/25/9
1
SPECIAL SHIPPING NOTES: 1MDG: Hydrogen Peroxide and Peroxyacetic Acid Mixtures,
with Acids, Water and not more than 6%Peroxyacetic Acid, Stabilized
IATA: Hydrogen Peroxide and Peroxyacetic Acid Mixtures, with Acids, Water and not more than 6%
Peroxyacetic Acid, Stabilized
Protect against physical damage. Use proper personal protective equipment and positive pressure self
contained breathing apparatus when handling spills or leaks. Dike any spills.
........................_....--...........--.-._._..... -- —---......_..._....._......._....._._................ ........._...................... .....
._..
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT)
SECTION 311 HAZARD CATEGORY (40 CFR 370): Fire Hazard, Immediate
(Acute) Health Hazard
SECTION 312 THRESHOLD PLANNING QUANTITY (40 CFR 370): 500 lbs.
SECTION 313 REPORTABLE INGREDIENTS (40 CFR 372): Listed, Peracetic
Acid 5%
SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS
SUBSTANCES (40 CFR 355): Listed (Peracetic Acid), Planning Threshold = 500 lbs.
SECTION 302.4 REPORTABLE QUANTITY (40 CFR 355) The following is a list
of the ingredients that are listed.
Chemical Name
Peroxyacetic Acid
RO
500 lbs.
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT)
CERCLA REGULATORY (40 CFR 302.4): Listed (Acetic Acid), Category D
5% Peracetic Acid (Unlisted), RQ = 1001bs., Corrosivity, Reactivity
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT): Listed.
Chemical Name
Acetic Acid
Wt.%R
10- 115000 lbs.
RC.RA STATUS: Waste No. D002, Waste No. D003
WHMIS (WORKER HAZARDOUS MATERIALS INFORMATION
SYSTEM): Product Identification No.: 9183
Hazard Classification: Class D, Div. 2, Subdiv. B, Class E (Corrosive), Class C (Oxidizer),
Ingredient Disclosure List: Listed
16. OTHER INFORMATION
http://msds.prineeton.finc.com/msds/2477hj lj.litm 06/25/9F
CHRONIC EFFECTS FROM. OVEREXPOSURE: No data available for the product.
Product contains hydrogen peroxide. 'there are reports of limited evidence of carcinogenicity of
hydrogen peroxide to mice administered high concentrations in their drinking water (IARC
Monograph 36, 1985). However, the International Agency for Research on Cancer concludes that
hydrogen peroxide could not be classified as to its carcinogenicity to humans (Group III
Carcinogen).
CARCINOGENICITY
Chemical Name NTP IARC OSHA Other
Status Status Status
Hydrogen Peroxide Not Not listedNot listed (ACGIH) Listed (A3,
listed Animal Carcinogen)
....... - ................... .............. ......... ...
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION: 96-hr. LC50 = 1.6 mg/L (Rainbow trout)
[FMC I95-20231 96-hr. LC50 = 1.1 mg/L (Bluegill sunfish) [FMC I95-2029]
48-hr. EC50 = 0.73 mg/1(Daphnia magna) [FMC I95-20211
120-hr. EC50 = 0.18 mg/L (Selenastrum, green algae) [FMC I95-2027]
CHEMICAL FATE INFORMATION: Peracetic acid is completely miscible with water.
Aqueous solutions of peracetic acid hydrolyzes to acetic acid and hydrogen peroxide with a half
life of 3-5 days.
-- - -- --- ----...- --- - ------.........
13. DISPOSAL CONSIDERATIONS
1 DISPOSAL METHOD: Dilute with at least twenty volumes of water and allow the
J hydrogen peroxide it contains to decompose, followed by discharge to a suitable treatment system
in accordance with appropriate govenunental regulations.
14. TRANSPORT INFORMATION
U.S. DOT (DEPARTMENT OF TRANSPORTATION)
OTHER SHIPPING INFORMATION: DOT (DEPARTMENT OF
TRANSPORTATION)
PROPER SHIPPING NAME: Hydrogen Peroxide and Peroxyacetic Acid Mixtures, Stabilized
with Acids, Water and not more than 6% Peroxyacetic Acid
PRIMARY HAZARD CLASS/DIVISION: 5.1 (Oxidizer), Subsidiary: 8 (Corrosive)
UN/NA NUMBER: UN 3149
PACKING GROUP: 11
PLACARDS: Bulk: 5.1 Oxidizer
LABEL: Oxidizer and Corrosive
OTHER SHIPPING INFORMATION:
DOT Marking: Hydrogen Peroxide and Peroxyacetic Acid Mixtures, Stabilized with Acids, Water
and not more than 6% Peroxyacetic Acid, UN 3149
Hazardous Substance/RQ: Not applicable
49 STCC Number: Not required - no rail shipments
Material is shipped in 5 gal. (45 lb.), 30 gal. (250 lb.), and 55 gal. (450 lb.) vented polyethylene
drums and linear (not cross linked) polyethylene IBC's.
http://msds.princeton.fmc.com/nisds/2477hj l j.htm 06/25/9f
NIEL11NG FOIN`1':-25.9°C (-14.6°F)
SOLUBILITY IN WATER: (% by wgt.) @ 250C (77017): 100
EVAPORATION RATE: (Butyl Acetate = 1) Above 1
DENSITY: 9.17 lbs./gal
SPECIFIC GRAVITY: (H20=1): 1.10 @ 200C
COEFF. OILIWATER: Not available
ODOR THRESHOLD: Not available
OXIDIZING PROPERTIES: Oxidizer
COMMENTS: pH (1% solution) @ 25°C: 2-3
Self Accelerating Decomposition Temperature (SADT) > 55°C (55 gallon drum)
........._- ........._._.._..._.._.. -- - - _--------- --
10. STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Open flames, elevated temperatures, any source of heat,
combustibles such as paper and wood and contamination.
STABILITY: Stable (expected shelf life - 1 year, when stored at temperatures below 86°F).
:POLYMERIZATION: Will not occur
:HAZARDOUS DECOMPOSITION PRODUCTS: Acetic acid and oxygen that
supports combustion.
INCOMPATIBLE MATERIALS: Dirt, alkali, reducing agents, organics and heavy
metals such as iron, copper, chromium, aluminum, cobalt and caustic.
-- - _..._.. --- — _.__ _.._._ ..-._.
11. TOXICOLOGICAL INFORMATION
EYE EFFECTS: Severely irritating [FMC Study 195-2036]
SKIN EFFECTS: Severely irritating [FMC Study I95-20351
DERMAL LDS,: No data available for the product. 17% Peracetic Acid: LD50 >200 mg/kg
(rabbit) [FMC 183-721 ]
ORAL LDS,: 1922 mg/kg (rat)
INHALATION LCS,: No data available for the product. LC50 = 524 mg/m3 (mouse, 1-hour)
[J. Hyg. Epidemiol, Microbiol. Immunol. 20:54, 1976]
TARGET ORGANS: Eyes, skin, nose, throat, lungs
ACUTE EFFECTS FROM OVEREXPOSURE: Liquid may cause severe burns and
irreversible tissue damage to eyes, including blindness. Inhalation of peracetic acid vapors causes
lacrimation and irritation of the mucous membranes, eyes and nasal passages.
http://msds.princeton.fmc.com/msds/2477hj 1 j.htm 06/25/9
7. HANDLING AND STORAGE
HANDLING: Transfer product from drums to process in closed system (hermetically) and if
1 not possible use effective local exhaust ventilation. Empty drum as thoroughly as possible. Triple
rinse before disposal. Avoid contamination; impurities accelerate decomposition. Never return
product to original container. Use airless spray to minimize mist generation.
STORAGE: Do not store near reducing agents, fuels or other non -compatible materials. Storc
in a cool (less than 86°F), dry, well ventilated area. Do not store in direct sunlight, or near source
of ignition or heat. Do not double stack. Use first in, first out storage system. Containers must be
vented. Expected shelf life - 1 year.
COMMENTS: VENTILATION: Provide mechanical local exhaust ventilation to prevent release
of mist into the work area. If ventilation is inadequate or not available use acid gas cartridge or.
canister with full facepiece.
._...-..._._._.. ...__..__..._..--............ .._.-__._...---.-.........._--... --....-------- --_ ----- ....- - ..._....-...........-- -- - _----..._.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE LIMITS
TWA STEL/Ceiling PEL STEL/Ceiling
Chemical Name A{ CGIH) ACGIH (OSHA) (OSHA)
.
Hydrogen Peroxide I ppm 1 ppm
Acetic Acid 10 ppm 15 ppm 10 ppm
ENGINEERING CONTROLS: Provide mechanical local exhaust ventilation to prevent
release of mist into the work area. If release is expected use respiratory protection.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Use cup type chemical goggles. Full face shield may be used.
RESPIRATORY: Use approved acid/gas cartridge or canister with full facepiece unless
break -through occurs, then use airline supplied or self contained breathing apparatus with full
facepiece.
PROTECTIVE CLOTHING: Rubber or neoprene gloves and footwear. Rubber or neoprene
aprons or full protection clothing.
..............
9. PHYSICAL AND CHEMICAL PROPERTIES
ODOR: Sharp, pungent, vinegar like odor
APPEARANCE: Colorless liquid
pH: Less than 1
PERCENT VOLATILE: 99
VAPOR PRESSURE: 22 rnm Hg @ 25°C
VAPOR DENSITY: (Air = 1): Not available
BOILING POINT: About 990C (210°F)
http://msds.princeton.fmc.com/msds/2477h.i 1 j.htm 06/25/9f
4. FIRST AID MEASURES,
EYES: Immediately flush with water for at least 15 minutes, lifting upper and lower eyelids
(, intermittently. See a medical doctor immediately.
SKIN: Remove contaminated clothing and thoroughly wash with soap and water. If irritation
occurs and persists, contact a medical doctor.
INGESTION: Rinse mouth with water. Dilute by giving 1 or 2 glasses of water. Do not induce
vomiting. Never give anything by mouth to an unconscious person. See a medical doctor
immediately.
INHALATION: Remove to fresh air. If breathing discomfort occurs and persists, see a
medical doctor. If breathing has stopped, give artificial respiration and see a medical doctor
immediately.
NOTES TO MEDICAL DOCTOR: This product can be corrosive to skin, eyes and
mucous membranes. Consideration should be given to careful endoscopy as stomach or
esophageal burns, perforations or strictures may occur. Careful gastric lavage with an
endotracheal tube in place should be considered. Observation may be warranted. Treatment is
controlled removal of exposure followed by symptomatic and supportive care.
.._..-...._....------- ..-..- - ---- - - -- ......... .._...._...... .._... _ _-----._._...._.... --.._._.�_.___.._...-........... .._...-- -----
5. FIRE FIGHTING MEASURES
FLASHPOINT AND METHOD: Approximately 182°F (83°C) - closed cup
FLAMMABLE LIMITS: Not available
.1
r / AUTOIGNITION TEMPERATURE: 270°C (518°F)
EXTINGUISHING MEDIA: Use water spray to keep fire exposed containers cool.
Extinguish fire using agents suitable for nearby fires.
EXPLOSION HAZARDS: Oxygen that can initiate or promote combustion.
FIRE FIGHTING PROCEDURES: Use flooding quantities of water only. Use water
spray to keep fire exposed containers cool. Fight fire from protected location or maximum
distance. Chemical type extinguishers are not effective with peracetic acid or hydrogen peroxide.
lJse proper personal protective equipment and positive pressure self contained breathing
apparatus.
SENSITIVITY TO STATIC DISCHARGE: Not available
SENSITIVITY TO IMPACT: Not available
HAZARDOUS DECOMPOSITION PRODUCTS: Oxygen that supports combustion
and acetic acid.
-.__................................._......_.................-_..._...- --...__.._._.__...___.__.......-----____- _.. - _ ----......_._........_........._............-..... _._....... ....... ...-..._............... ....
6. ACCIDENTAL RELEASE MEASURES
RELEASE NOTES: Approach release from upwind. Stop or control leak using special
protective clothing and positive pressure self-contained breathing apparatus. Control run off and
isolate discharged material for proper disposal. Do not allow undiluted material to enter storm or
sanitary sewer systems.
http://msds.princeton.fmc.com/msds/24774i l j.htm 06/25/9
MATERIAL. SAFETY DATA SHEET
VigorOirm Liquid Sanitizer
MSDS Ref. No: 79-21-0-4
Version: US/Canada
r :r; Date Approved: 03/04/1998
Revision No: 3
1. CHEMICAL PRODUCT AND COMPANY
IDENTIFICATION
PRODUCT NAME: VigorOxTM Liquid Sanitizer
SYNONYM(s): Peroxyacetic Acid Solution, Peracetic Acid Solution
GENERAL USE: EPA Registration No. 65402-1
VigorOxTM has been'formulated for use in the circulation cleaning and sanitizing of equipment such
as tanks, pipelines, evaporators, fillers, pasteurizers, and aseptic equipment in dairies, wineries,
breweries and beverage plants.
MANUFACTURER
FMC Corporation
Active Oxidant Division
1735 Market Street
Philadelphia, PA 19103
General Information: (215) 299-6000
Emergency Telephone
Numbers:
CHEMTREC (800) 424-9300
Emergency Phone (303) 595-9048
(Medical) Call Collect.
Emergency Phone (716) 879-0400
(Plant/Other) Call Collect
2 COMPOSITION / INFORMATION ON INGREDIENTS -
Chemical Name
CAS #
Wt.%
Peroxyacetic Acid
79-21-0
5 - 6
Hydrogen Peroxide
7722-84-1
22 - 23
Acetic Acid
64-19-7
10 - 11
Water
7732-18-5
63 - 65
.-.......--_---- - - ..._.. _-.-._....- - - - _..... ---------- ---_- _ _--------.----------- ---- _...___... -- .-..-_...
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
IMMEDIATE CONCERNS: Oxidizer: Stabilized peracetic acid decomposes under fire
conditions to release oxygen that intensifies the fire. Use water to keep fire -exposed containers
cool.
POTENTIALHEALTH EFFECTS: Liquid and mist are corrosive (causing burns); direct
contact could cause irreversible damage to eyes including blindness and/or irreversible destruction of
skin tissue. Vapor/mist will irritate nose, throat and lungs but will usually subside when exposure
ceases.
I
http://msds.princeton.fmc.com/msds/24771ij l j.htm 06/25/9f
https:Hportal.newbelgium.com:1494/hnsdsfind/tnsdsdata/ 16168277. HTM
Avoid contamination of food, feed, waterway, or groundwater. If possible, capture material and contain for re -use or
disposal. Alternatively, absorb into earth, clay, sawdust, or commercial absorbent, and contain for disposal.
Remainder may be neutralized with baking soda (some Carbon Dioxide gas will evolve) or lime, then rinsed to a
sewer.
9. WASTE DISPOSAL CONSIDERATIONS
Dispose in approved landfill according to Federal, State, and Local Regulations.
10. HANDLING AND STORAGE
Do not contaminate food, feed, or natural water. Keep container closed when not in use. Store in a cool, dry
location. RELEASES HEAT WHEN MIXED WITH WATER. Supplier not responsible for disposition of this
product. Do not reuse container. Maintain an eyewash station and safety shower in product handling areas.
11. EXPOSURE CONTROLS / PERSONAL PROTECTION
Eye Protection Splash Goggles
Skin Protection Impermeable Gloves and Synthetic Apron. Wash exposed areas after handling.
Respiratory Protection NIOSH approved self contained breathing apparatus for exposure above PEL.
Ventilation General exhaust acceptable if PEL not exceeded.
12. TSCA CERTIFICATION
Birko Corporation certifies that all ingredients in this chemical formulation comply with all applicable rules or
orders under TSCA and that we are not offering a chemical substance for entry in violation of TSCA or any
applicable rule or order under TSCA.
13. APPROVALS
Reason for Issue Amendments
Prepared By Dana Johnson, Formulator
Approved By Mike S. Brown
Title Chief Operating Officer
Supercedes Date 1/16/2004
MSDS Number EXP12
4 of 8/8/2005 1 1:39 AM
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HMIS
Personal Protective Index
0 FLAMMABILITY'
A
E l h
2 HEALTH
B
F J I_...
2 REACTIVITY
C I
G F
I K
J PCI"sonal Protection
D
I
H I
X Ask your supervisor
Hazard Index
CO.,..Fmc
lassSLidJ
Afaine
Spl91 Htwl a, Gloves
Goggles M1tasA
S,'hox Nm Vapor Vapor Full Suit I 10
AVnm Rapinlor R4phmor Rapiramr
4 - Severe
- I
-
I I i..
I I- I-
3 - Serious
.
i ..
2 - Moderate
I - Slight
n - Minimal
6. POTENTIAL HEALTH EFFECTS
Routes of Entry Eye contact, Skin contact, Inhalation, higestion
Ingredients in this product are toxic when inhaled. Mist from this product, or its solutions,
Acute / Chronic will bum nasal, mucosal, bronchial passages and lung tissue. Acute exposure beyond the
Inhalation established TLV can result in Prolonged exposure above PEL may be fatal.Long term
exposure beyond the established TWA or PEL can contribute to Prolonged exposure above
PEL may be fatal.
Acute / Chronic Skin This product, or its working solutions will bum skin on contact.
Contact .
Acute / Chronic Eye Burns on contact. Can cause blindness if not promptly treated.
Contact
Ingestion Causes burns of gastrointestinal tract. Harmful or fatal if swallowed.
7. FIRST AID MEASURES
Inhalation Remove from exposure. Administer oxygen if breathing is difficult. Resuscitate if necessary.
Get medical help immediately.
Immediately drench with flowing water for at least 15 minutes. Remove contaminated
Skin Contact clothing as quickly as possible. Launder before reuse. Destroy contaminated shoes. Medical
treatment for all burns must begin immediately, no matter how minor they seem.
Eye Contact Immediately rinse eyes thoroughly in cool running water for at least 15 minutes. Get medical
attention at once, preferably from opthamologist.
Ingestion DO NOT induce vomiting. Have a conscious victim drink milk or water to dilute. Never give
an unconscious person anything by mouth. Get medical help immediately.
8. ACCIDENTAL RELEASE MEASURES
3 of 8/8/2005 11:39 AM
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Odor
Sour
Boiling Point
212-2200 F
Freeze Point
20-250 F
Water Solubility
Complete
Specific Gravity
1.094
Vapor Pressure
< I
Vapor Density
Evaporation
Rate
>I
Not established
NFPA Ratings
Blue- Ilealth Hazard
4-,Dcadly
3-d3xtrcmc Danger
2--1Hazardous
I - Slightly Hazardous
0 - Insignificant Hazard
Red - Fire Hazard
4- Flash Point < 73°F
3 - Flash Point > 73°F and < 100°I'
2- Flash Point > 100°I' and < 200°F
1 - Flash Point > 2000I'
0 - Noncombustible
4. FIREFIGHTING MEASURES
Flash Point Not Applicable
Yellow - Reactivity
4 - May Detonate
3 - Shock or Heat may Detonate
2 - Violent Chemical Change
I - Unstable If Heated
0 - Stable
Extinguishing Media Water, Carbon Dioxide, Dry Chemical , Foam Blanket
White - Specific Hazard
ACID - Acid
ALK - Alkali
COR - Corrosive
OXY - Oxidizer
1' - Polymerization
^ ^ - Radioactive
- Use No Water
Special Procedures Always wear self - contained breathing apparatus when fighting a chemical fire.
Unusual Nitrogen Oxides (Toxic!) liberated during combustion. Phosphorus Oxides (possibly toxic)
Fire/Explosion Hazard liberated during combustion.
5. REACTIVITY
This product should maintain its physical character when stored closed at moderate
Stability temperatures, between 28 °F and 105 'F.
Hazardous This product does not polymerize under normal storage and use conditions.
Polymerization
Incompatible Strong Alkali, Oxidizable, or Organic Matter (Oil, Wood, Cotton, etc.), Heat, Cyanides,
Materials Chlorine Compounds, Amphoteric Metals (Aluminum, Brass, Copper, Tin, Zinc)
Decomposition Nitrogen Oxides (toxic!) liberated during combustion. Phosphorus Oxides (possibly
Products toxic) liberated during combustion.
2 of 8/8/2005 1 1:38 AM
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MSDS - NBB Acid Clcaner #1 A 1/16/2004
MATERIAL SAFETY DATA SHEET
BIRKO Corporation
1. CHEMICAL PRODUCT AND COMPANY
IDENTIFICATION
Product Name: NBB Acid Cleaner #lA
Product Code: EXP12
Manufacturer Emergency Phone Numbers
1311ZKO Corporation
9152 Yosemite Street Transportation:
I-lenderson, CO 80640 CHEMTREC (800) 424-9300
(303)289-1090
www.birkocorp.com Non -Transportation:
BIRKO (303) 289-1090
(800)525-0476
2. COMPOSITION / INFORMATION ON INGREDIENTS.
CAS # Component Percent
Exposure Limit
07697-37-2 Nitric Acid 11 12
PEL
2 ppin (2)
STEL
4 ppm
ACGIH
2 mg/M3
TWA
IDLH
4 ppm
07664-38-2 Phosphoric Acid (3) 4
PEL
1 mg/M3 (4)
STEL
3 nig/M3
ACGIH
I mg/M3
TWA
IDLH
0.75 ppm
(1) The RQ for this component is 1000 pounds of active ingredient. The TPQ for this
component is 1000 pounds of active ingredient. This product contains the above toxic
chemicals as percent by weight subject to the reporting requirements of Section 313 of
the Emergency Planning and Community Right -to Know Act of 1986 and 40 CFR
372. (2) oxidizer/corrosive (3) The RQ for this component is 5000 pounds of active
ingredient. This product contains the above toxic chemicals as percent by weight
subject to the reporting requirements of Section 313 of the Emergency Planning and
Community Right -to Know Act of 1986 and 40 CFR 372. (4) corrosive
3. PHYSICAL AND CHEMICAL
PROPERTIES
Physical Form Liquid
Color Colorless -Light Yellow
1 of 8/8/2005 11:38 AM
Harcros Chemicals Inc
Kansas city, Kansas
MATERIAL
SAFETY DATA SHEET
Page 6
_____......
___________Y__nf____________.__
PRODUCT NAME
---------------------------------------
NBB CAUSTIC/LCA
BLEND # 1
Date: 12-MA,-2004 12:29:45.65
PRODUCT CODE
--""'--""'_"'__'__
18636
-----------------
BULK/#
------------------------------------------------------
---------------------------------------------------
NAME:
GENE TURNER
_____________________
DATE ISSUED: 040427
DATE REVISED: 040427
< = LESS THAN
N/A = NOT
APPLICABLE
LINK = UNKNOWN
>. = MORE THAN
N/D = NOT
DETERMINED
N/E = NOT
ESTABLISHED
The information provided in this Material Safety data sheet has been obtained from sources
believed to be reliable. Harcros Chemicals Inc provides no warranties, either expressed or
implied and assumes no responsibility for the accuracy or completeness of the data contained
herein. This information is offered for your information, consideration , and investigation.
You should satisfy yourself that you have all current data relevant to your particular use.
Harcros Chemicals Inc knows of no medical condition, other than those noted on this material
safety data sheet, which are generally recognized as being aggravated by exposure to this product.
Harcros Chemicals Inc
Kansas City, Kansas
MATERIAL SAFETY DATA SHEET Page 5
-------------------------------------- '-------------------------------
PRODUCT NAME : NBB CAUSTICACA BLEND # 1 Date: '2-M4Y-2004 12:29:45.29
PRODUCT CODE : 18636 BULK/#
SECTION VII SPILL AND LEAK PROCEDURES (CONTINUED)
------------------------------
SECTION VIII
Proper Shipping Name: SODIUM HYDROXIDE SOLUTION
Hazard Class: 8, UN1824 PGII
Label Requirements: CORROSIVE
Reportable Ouantiiy: 2000 Lbs shipments are reportable
SECTION IX ADDITIONAL INFORMATION
---------------------------
LABEL SIGNAL WORD
DANGER
PRECAUTIONS
Wear protective equipment when handling. Use only with adequate ventilation. Wash thoroughly
after handling. Do Not breathe dust. Do Not breathe vapor, mist, or dust. Do Not get in eyes,
on skin, or clothing.
Do not swallow.
HANDLING
Keep away from acids. For -industrial use only. When diluting, add product slowly to water With.
agitation. Heat is generated upon dilution with water. Addition of water can cause violent
splashing. ATTENTION: This container hazardous when emptied. Sinceemptiedcontainer contains
product residues (vapor or liquid), all Labeled .hazard -'precaution s must be observed.
STORAGE
Keep container closed when not in use. Store in cool dry place. Product can cause corrosion
of iron and steel at elevated temperatures. Keep out of reach of children.
------------------------------
SECTION X COMPLIANCE INFORMATION
NSF INFORMATION
MAXIUM USE LEVEL IN POTABLE WATER:
For 50% Caustic Soda (50% Sodium Hydroxide)-: 100 mg/L, For 25% Caustic Soda (25% Sodium
Hydroxide): 206 mg/L.
Continued On Page 6
Harcros Chemicals !no
Kansas City, Kansas
MATERIAL SAFETY DATA SHEET Page 4
------ ..------------------------------- I ------------- -- --'___----__-
PRODUCT NAME NEB CAUSTIC/LCA BLEND 4 1 Date: 12-M.AY-2004 12:29:44.96
PRODUCT CODE : 186336. BULK/A`
--- - - ------ -----=- -------'--------------------------------------
SECTION V PHYSICAL DATA (CONTINUED)
Vapor Pressure (MM. HG-): > OR = 6.300 a 104 deg. F
Vapor Density (AiR=1) : N/D
Evaporation Rate ( NA =1): N!D
Solubility in Water:: COMPLETE
Percent Volatile by Volume: N/D
pH: aqueous approx. > OR = 13.000
Appearance:
COLORLESS TO LIGHTLY COLORED LIQUID
Odor :
NIL
--------------------------
SECTION VI REACTIVITY DATA
STABILITY
Stable
INCOM_PATASILITY
amphoteric metals halogenated hydrocarbons inorganic acids organic acids Avoid contact with
amphoteric. metals whichinclude aLkinum, copper, zinc, and brass. Contact with water will
generate: heat, cause violent splashing and spattering. .
Contactwith some.metais can, generate explosive hydrogen .gas.
HAZARDOUS POLYMERIZATION
Witl not occur
------------------------------
SECTION VII SPILL AND LEAK PROCEDURES
.STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
Evacuate non essential personnel, :etimnateeignition sources, and wear protective equipment (Bee
Section 111)_ Shut off source of teak only it safe to do so. -Contain spill. Recover free
product. To clean up residue, ftush sparingly with water or use an absorbent. Avoid runoff to
ground water, surface waters, and sewers. It may be necessary to remove contaminated soil. If
product is flammable or combustible, use non sparkirg tools. If acidity (low pH) is a problem,
neutralize with hydrated time, soda ash, or sodium bicarbonate. if alkalinity (high pH) is a
problem neutralize with dilute acetic acid or dilute hydrochloric (muriatic) acid. If required,
notify state and local authorities
DISPOSAL METHOD
Solids must be disposed of in a permitted waste management facility. Recovered liquids may be
reprocessed or incinerated. incineration must be handled in a permitted facility. Dispose of
material in accordance with all Federal, State and local regulations. Local regulations may be
more stringent than FederaL or State.
Continued On Page 5
Harcros Chemicals Inc
Kansas City, Kansas
MATERIAL SAFETY DATA SHEET Page 3
-----""-'------------------- .'----"'----------.----,-------------------------------------
PRODU'CT NAME : NBB.CAUSTICAC.4 BLEND # 1 Date.: 12-MAY-2004 12:29:44.62
PRODUCT CODE : 19636 BULK/#
SECTION III SPECIAL PROTECTION (CONTINUED)
----------------------------
PROTECTIVE EQUIPMENT
PROTECTIVE EQUIPMENT EYES ,
chemical goggles faceshield
PROTECTIVE EQUIPMENT SKIN
impervious gloves clean body covering clothing
PROTECTIVE EQUIPMENT INHALATION
Tf exposure limits are exceeded, or if exposure may occur, use NIOSH/MSHA respirator approved
for your conditions of exposure. Refer to the most recent NIOSH publications concerning chemical
hazards, or consult your safety equipment supplier. Respiratory protection programs must be in
compliance with OSHA requirements in 29 CFR 1910.134. For emergencies, a NIOSH/MSHA approved
positive pressure breathing apparatus should be readily available.
VENTILATION REQUIRED:
Adequate venti-lation is required to minimize exposure. or to maintain exposure levels below
OSHA/ACGIH requirements. Local mechanical ventilation maybe required.
ADDITIONAL PROTECTIVE MEASURES
(Safety shouer,,.eye wash fountain, and washing facilities should be readily available. In case
of emergency or when dusting, misting, or splashing may occur, wear respiratory protection, eye
protection, gloves, helmet, boots, and,comiplete protective body covering.
SECTION IV FIRE & EXPLOSION HAZARD DATA
---------------------
flash Point (METHOD): > OR = N/A
Flammable Limits (Y. Volume in Air) UPPER: N/D _ Lower: N/D
EXTINGUISHING MEDIA
water fog foam carbon dioxide dry chemical media appropriate for surrounding fire
F. IRE FIGHTING PROCEDURES
Not considered a fire hazard. Prevent human exposure to fire, fumes, smoke, and products of
combustion. Evacuate non essential personnel. Firefighters should wear full face, self.coniained
breathing apparatus and impervious protective clothing. Do not use'a direct stream of water.
UNUSUAL FIRE & EXPLOSION HAZARDS
none currently known
SECTION V PHYSICAL DATA
-------------------------
Boiling Point: >OR = 293 deg. F
Freezing Point: N/D
Specific Gravity (H(2)0=1): > OR = 1.5300 a 60 deg. F
Continued On Page 4
Harcros Chemicals Inc
Kansas City, Kansas
MATERIAL SAFETY DATA SHEET Page 2
- __________ ______'_---
PRODUCT NAME NBB CAUSTICJLCA BLEND r 1 Date: 12-MAY-2004 12:29:44.25
PRODUCT CODE 18636 BULK(# -
SECTION It HEALTH HAZARDS (CONTINUED)
HAZARD OVERVIEW: DANGER! CORROSIVE LIQUID. CAUSES BURNS. DESTROYS BODY TISSUES.
EYES
Eyecontact with product may cause burns tissue destruction eye damage blindness
SKIN
Skin contact may cause burns tissue ulceration skin damage Effects may be delayed.
INHALATION
inhalation may cause irritation nausea headache dizziness pain decreased breathing capacity
tissue destruction internal bleeding lung damage, damage to respiratory system chemical
pneumonia Aspiration (breathing) of liquid, mist, or vomitus (vomit) into Lungs can cause
aspi-ration (chemical) pneumonia, hemorrhaging (bleeding), Lung damage, and even death. Symptoms
of aspiration pneumonia include coughing, labored breathing and bluish skin.
INGESTION
Ingestionmay cause diarrhea vomiting burnstissue ulceration internal bleeding even death
TARGET ORGANS
OVEREXPOSURE MAY CAUSE DAMAGE TO,
DISORDERS OF, OR ADVERSELY AFFECT THE FOLLOWING SYSTEMS, FUNCTIONS, ORGANS: destruction of all
body, tissues
FIRST AID
FIRST AID EYES
Immediately flush eyes with plenty of water for at Least .15 minutes, white holding eyelids apart
to ensureflushingof entire surface_ Call a physician.
FIRST AID SKIN
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated
clothing and shoes. Thoroughly clean clothing before reuse. Discard contaminated shoes and
contaminated leather articles. Call a physician.
FIRST AID INHALATION
Remove to fresh air. If not breathing give artificial respiration, preferably mouth to mouth.
if breathing is difficult give oxygen. Call a physician.
FIRST AID INGESTION
Do not induce vomiting. Rinse mouth with water. Dilute stomach contents by drinking water, if
vomiting occurs spontaneously, keep head below hips to prevent breathing vomitinto lungs. Call
a physician immediately.
OTHER INFORMATION
ROUTES OF ENTRY
eye contact skin contact
OVEREXPOSURE MAY AGGRAVATE DISORDERS OF THE
skin Lungs respiratory system
CARCINOGEN STATUS
No components, present in excess of 0.1% by weight are listed as carcinogens by. IARC, NTP, or
OSHA.
SECTION ]iI SPECIAL PROTECTION
Continued On Page 3
Harcros Chemicals Inc
Kansas Cizy, Kansas
MATERIA; SAFETY DATA SHEET Page l
PRODUCT NAME : .BB CAUSTICJLCA BLEND # 1 Date: 12-MAY-20C4 12:29:43,92
PRODUCT CODE : 18636 BU`K/#
_ --'_"'-----'-----'
_- -_____
--------CAS 9:---' u/A
hiSDS Nc. 003881 Revision No./Date 01 040427
Detail Number 02290/01
FORMULA:
CHEM. FAMILY: inorganic bases
CHEMICAL NAME AND SYNONYMS:
Caustic Soda Blend
Liquid: Caustic Soda/LCA,Blend
MSDS G03881 Detail 02290
SUPPLIERS NAME.: Harcros Chemicals Inc.
5200 Speaker Road
Kansas City KS 66106-1095
SUPPLIERS PHONE .NUMBER : 913-321-3131
TRANSPORTATION EMERGENCY PHONE NUMBER 1-800-424-93CO
S.A.R.A..INFORMATION
HAZARDS : Acute Reactivity Chronic
PHYSICAL DATA : Mixture. liquid
SECTION I HAZARDOUS INGREDIENTS
_.
--------
ingredient
MAX
SARA
AIR CON TAMIN'e NT LEVELS
'Cas Number
;%
APPLIES
TWA/TLV STEL CEIL AGENT
W/W
312 313 372
(ppm) (PPm)---11pp(n- >---- ----_'
--------- I -SKIN( -
--- - ---
caustic Soda
----
50.0.
- --
Y N. N
As Sodium Hydroxide
Sodium MydrPXide
TWA/TLV 2 mg/m3 (Ceiling) OSHA/AGGIH
(CAS # 1310-73-2 )
Caustic Potash
Potassium Hydroxide
0.3
Y N N
As Potassium Hydroxide
TWA/TLV 2 mg/m.(ceiling) OSHAJACGPH
(CAB # 1310-58-3
Potassium Silicate
0.0
Y N N
OCAS # 1313-76-1 )
-----------------
-----
---------- 1----------- I------ I I -
SECTION II HEALTH HAZARDS
------------------------------
POTENTIAL EFFECTS OF EXPOSURE
Continued On Page 2
ATAMMEN T S
B IN M
NEW BELGIUM BREWING
COMPANY PACKAGING
HALL
.au.wmr.
50% Design
Development
Landscape Plan
L400
0 New Belgium Brewing Company Inc.
500 Linden Street
Fort Collins, Colorado 80524 USA
Hazardous Materials Impact
Analysis - Packaging Hall Project
Attachment B: Facility Drawing Depicting the Location of Chemical Storage Area and the Pipe Bridge
NOTE: This is NOT a final construction drawing; it is used to illustrate the relative locations of the chemical storage room and the pipe bridge with respect to the larger
structure only.
Issued to: City of Fort Collins
Poudre Fire Authority
Rep. Name: Ron Gonzales
ile: CADocuments and SettinaslaimccolilDt
Packaging Hall Project
Issued by: Andrew Troccoli, NBB EH&S Mgr
Date of Issue: August 8, 2005 1
Page 5 of 5
New Belgium Brewing Company Inc.
500 Linden Street
Fort Collins, Colorado 80524 USA
Hazardous Materials Impact
Analysis - Packaging Hall Project
Attachment A: Hazardous Materials Stored in the Packaging Hall Chemical Storage Area
Product Name
Constituent[%w/w],CASRN
Max.
Amt
Avg.
Amount
Product
S.G.
1997 UFC
Classification
Construction& Containment, Notes
al
al
NBB CAUSTIC/LCA BLEND #1, Low
Sodium hydroxide [50%], 1310-73-2
HOPE on a spill pallet or double walled, filament -wound FRP with a compatible resin
Salt
Potassium Hydroxide [0.3%], 1310-58-3
150
75
1.530
Corrosive
(exact configuration TBD). Day tank. Product is Used in CIP systems to clean
Potassium Silicate <1%,1312-76-1
equipment and tanks.
Peroxyacetic acid [5%], 79-21-0
17.5 or
Dispensed directly from a 35 or 55-gallon drum. There may or may not be an extra
VIGOROX
Hydrogen peroxide [23%], 7722$4-1
35 or 55
27 5
1.100
Oxidizer
drum in reserve for short time periods (< 3 days). Drums are stored on a spill pallet.
Acetic acid 11%, 64-19-7
Used to clean equipment in non-CIP applications.
Phosphoric acid [4%], 7664-38-2
HOPE on a spill pallet or double walled, filament -wound FRP with a compatible resin
NBB ACID CLEANER #1A
Nitric gad [12%j. 7697-37-2
100
50
1.094
Corrosive
(exact configuration TBD). Day tank. Product is Used in CIP systems to clean
equipment and tanks.
CHEM N
Potassium hydroxide [5-10%], 1310-58-3
Sodium hydroxide [0-5%],1310-73-2
125
62.5
1.134
Corrosive
HOPE tank ti spill pallet. General-purpose foaming, chlorinated, caustic cleaner.
stir Fo er
Caustic Foamer
Sodium h ochlorite 0-5%, 7681-52-9
Used for reduction of microbes on exterior surfaces of vessels, pipes and the facility.
u
CHEMSTATION 9388
Phosphoric acid [ 10-15%1, 7664-38-2
125
62.5
1.066
Corrosive
HOPE tank on a spill pallet. General-purpose foaming acid cleaner. Used for
Acid Foamer
Citric acid 0-5% , 77-92-9
reduction of microbes on exterior surfaces of vessels, pipes and the facility.
CHEMSTATION 3902
Non -Hazardous
125
62.5
1.D26
N/A
HOPE tank on a spill pallet. Used for cleaning floors and other surfaces where
General Pu ose Cleaner
reduction of microbes is not critical.
CHEMSTATION 3687
Non -Hazardous
125
62.5
1.044
N/A
HOPE tank on a spill pallet. Water -based FCC/food grade lubricant for packaging
FCC Grade Track Lubricant
equipment bottle -tracks.
Figure 1
Example of a 125-gallon "Chemstation Tank" used to store
Chemstation product numbers 3205, 3687, 3902 and 9388.
www.Chemstation.com
Issued by: Andrew Troccoli, NBB EH&S Mgr
City of Fort Collins
Issued to: Date of Issue: August 8,2005
Poudre Fire Authority Packaging Hall Project
Rep. Name: Ron Gonzales Page 4 of 5
File: C:1Documents and ServingslatroccollDesktoplPackaging HalhHMINHMIA - Packaging Hall Expansion (Summer 2005).doc
ONew Belgium Brewing Company Inc. Hazardous Materials Impact
500 Linden Street
Fort Collins, Colorado 80524 USA Analysis - Packaging Hall Project
5.0 INCIDENT MANAGEMENT TEAM —EMERGENCY RESPONSE
5.1. Ni maintains a. team of up to twenty employees that are capable of responding to all on -site chemical releases and other critical
incidents.
5.2. Team members are trained to the OSHA HAZWOPR level 3 (defense and mitigation) and HAZWOPR level 5 (incident command)
standards.
5.3. At any given time, four employees are on -call to respond to hazardous material releases and other critical incidents.
5.4. NBB maintains a contract with a third -party company specializing in the mitigation of chemical releases in the event that additional
resources are required.
6.0 INCIDENT MANAGEMENT PLANS
6.1. The NBB document entitled "SPCC PLANS" contains information on chemical releases. Please reference this document for details
on chemical release defense and mitigation.
7.0 SIGNATURE BLOCK
The information contained in this document is true and accurate to the best of my knowledge as of the date of this document
and is consistent with best management practices for chemical handling.
Andre T. Troccoli, CHMM # 11426
EH&S Manager
Issued to: City of Fort Collins
Poudre Fire Authority
Packaging Hall Project
4)70cli
Date
Issued by:
Date of Issue:
Andrew Troccoli, NBB EH&S Mgr
August 8, 2005
Rep. Name: Ron Gonzales
Page 3 of 3
0 New Belgium Brewing Company Inc. Hazardous Materials Impact
500 Linden Street
Fort Collins, Colorado 80524 USA Analysis - Packaging Hall Project
3.3.2.4. This product contains nitric acid. Nitric acid is a strong oxidizer that will undergo decomposition into nitrogen oxides (NOx)
under high temperatures. Nitric acid is a strong acid; a one -percent solution has a pH of less than one and is corrosive to
organic material in addition to its oxidative properties.
3.3.3. Vigorox
3.3.3.1. This product will be used in relatively small volumes within the new packaging hall. The intention is to store this product in
its original vented -bung shipping container (35 or 55-gallon HDPE drum) on a spill pallet in the packaging hall chemical
storage area. This product will be dispensed from the drum.
3.3.3.2. The product will be used for automated CIP "clean -in -place" systems for equipment cleaning and sanitation.
3.3.3.3. Vigorox contains peroxyacetic acid, hydrogen peroxide and acetic acid. Both acetic acid and peroxyacetic acid are weak
organic acids. Peroxyacetic acid is also a strong oxidizer. Hydrogen peroxide is a strong oxidizer. Both hydrogen peroxide
and Peroxyacetic acid spontaneous decompose the decomposition is accelerated by heat, sunlight and contamination by
organic materials and some metals.
3.3.4. Chemstation Products
3.3.4.1. There are four Chemstation products (3205, 3687, 3902 and 9388) that are delivered on a periodic basis by Chemstation
located at 4800 Lima Street, Denver, Colorado. Chemstation delivers the product in a straight -truck in chemical totes. The
product is transferred from the chemical totes to day tanks using pumps and supply hoses that are stored on the
Chemstation truck when not in use. The Chemstation truck will park adjacent to the chemical storage room during
offloading. Delivery frequency is not yet determined.
3.3.4.2. Of the four Chemstation products, two (3687 and 3902) are non -hazardous and are listed in Attachment A for clarity but are
not classified under the 1997 UFC.
3.3.4.3. Chemstation 3205 is a chlorinated caustic foamer used to "foam" the exterior of equipment, floors and walls to reduce
microbial contamination. This product contains Sodium hypochlorite. Sodium hypochlorite is a strong oxidizer. When mixed
with hot water or acids, sodium hypochlorite produces oxygen and chlorine gas. When mixed with an acid, an exothermic
reaction takes place liberating heat and chlorine gas. When heated to decomposition, it will release sodium oxide (Na20) and
hydrogen chloride (HCI). Reactive with the following metals: aluminum, copper, zinc and brass. Sodium hypochlorite will
decompose over time liberating oxygen and chlorine gas; higher temperatures accelerate decomposition. This product also
contains potassium hydroxide, a strong base that is corrosive to organic material. The quantity of chlorine gas released
primarily depends on the amount of each chemical that comes into contact.
3.3.4.4. Chemstation 9388 is an acid foamer that will be used to "foam" the exterior of equipment, floors and walls to reduce
microbial contamination.
4.0 HAZARDS & POTENTIAL OFF -SITE IMPACTS
4.1. All chemicals stored in the packaging hall chemical storage area will be stored in appropriate containers with spill containment of at
least 110% of the volume of the largest container on the spill pallet. In addition, a valved stormwater collection point will be
located at the drainage point from the parking lot adjacent to the chemical storage area; the valve will be closed whenever
Chemstation or other companies or NBB staff are performing chemical transfers. The stormwater impoundment adjacent to this
location does have an outfall to the City stormwater sewer system and NBB is less than one mile from the river. While this is of
concern, the outfall is designed for large volumes of water. The risk of a hazardous material entering the environment from this
area is therefore low.
14.2. Chemstation 3205 & Chlorine Gas Production
4.2.1. There is a low probability of an offsite impact from the release of chlorine gas from this product. To prevent this occurrence, a
combination of strict segregation of this product with appropriate spill controls, containment, labeling, documented procedures
and training will be employed.
Issued by: Andrew Troccoli, NBB EH&S Mgr
Issued to: City of Fort Collins Date of Issue: August 8, 2005
Poudre Fire Authority Packaging Hall Project
Rep. Name: Ron Gonzales Page 2 of 3
File: C Cocuments and Settinaslatroccoli\Desktop\Packaging Hall\HMIA\HMIA - Packaging Hall Expansion (Summer 2005).doc
0 New Belgium Brewing Company Inc. Hazardous Materials Impact
Soo LindenStreet
Fort Collins, Colorado 60524 USA Analysis -Packaging Hall Project
1.0 PURPOSE & SCOPE
1.1. The purpose of this document is to set forth the proposed use and associated risks of the hazardous materials that will be stored
and used in the new packaging hall pursuant to section 3.4.5 of the City of Fort Collins Land Use Code.
2.0 EXISTING HAZARDOUS MATERIAL STORAGE & USE
2.1. This is a new building however, chemical storage and use in this new building will be similar to the existing packaging hall.
2.2. Please see the existing Hazardous Materials Management Plan (HMMP) for information on currently used hazardous materials at the
site.
3.0 PROPOSED HAZARDOUS MATERIAL STORAGE & USE
3.1. See Attachment A for a detailed list of hazardous materials that will be stored in the new facility. MSDS for these products are
attached.
3.2. See Attachment B for a drawing of the site depicting the chemical storage area and the pipe bridge.
3.3. Description of Product Storage and Use
3.3.1. NBB Caustic/LCA Blend #1
3.3.1.1. This product will be stored in a small permanent tank. Product will be transferred from the existing 8,000-gallon bulk tank in
the brewhouse-two chemical storage area via a pipeline. The frequency and volume of the transfers has yet to be
determined however, the idea is that this would be a "day tank" holding sufficient volume for use in a 24-hour period.
3.3.1.2. The product transfer line will be located on a pipe -bridge that originates at the bulk storage tank in the brewhouse two
chemical storage area, crosses the existing pipe bridge, up and over the roof of the warehouse and over two a new pipe
bridge that spans between the existing building and the new building. The pipeline will be marked appropriately and will
have secondary containment the entire length of the pipeline. The pipeline material will be 304-stainless steel with
secondary containment in the form of schedule-40 PVC.
3.3.1.3. The product will be used for automated CIP "clean -in -place" systems for equipment cleaning and sanitation.
3.3.1.4. This product contains sodium hydroxide. Sodium hydroxide can react with carbon dioxide to form carbonates which itself is
non -hazardous however, the rapid reaction creates a "vacuum" in an enclosed, sealed container. Sodium hydroxide is a
strong base; a one -percent solution has a pH greater than 1.0 and is corrosive to organic material.
3.3.2. NBB Acid Cleaner #1A
3.3.2.1. This product will be stored in a day tank. Product will be transferred from the existing outdoor, above ground 5,000-gallon
bulk storage tank in the CIP alley adjacent to the brewhouse-two chemical storage area via a pipeline. The frequency and
volurne of the transfers has yet to be determined however, the idea is that this would be a "day tank" holding sufficient
volume for use in a 24-hour period.
3.3.2.2. The product transfer line will be located on a pipe -bridge that originates at the outdoor above -ground bulk storage tank
adjacent to the brewhouse two chemical storage area, crosses the existing pipe bridge, up and over the roof of the
warehouse and over two a new pipe bridge that spans between the existing building and the new building. The pipeline will
be marked appropriately and will have secondary containment the entire length of the pipeline. The pipeline material will
most likely be Kynar (PVDF) with welded or flanged fittings although the final material selection is still pending. The
secondary containment material will most likely be either Kynar.or PVC although material selection is still pending.
3.3.2.3. The product will be used for automated CIP "clean -in -place" systems for equipment cleaning and sanitation.
Issued by: Andrew Troccoli, NBB EH&S Mgr
Issued to: City of Fort Collins Date of Issue: August 8, 2005
Poudre Fire Authority Packaging Hall Project
Rep. Name: Ran Gonzales Page 1 of 3
File: C,1Documems and SettingslatroccolilDesktoplPackaging Hall\H101WHMIA - Packaging Hall Expansion (Summer 2005).doc