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HomeMy WebLinkAboutNEW BELGIUM BREWERY, PROCESS WATER FACILITY - PDP - 1-95D - SUBMITTAL DOCUMENTS - ROUND 1 - HAZMATSHAZARDOUS MATERIALS MANAGEMENT PLAN NEW BELGIUM BREWING COMPANY FORT COLLINS, COLORADO 1.0 INTRODUCTION The purpose of this Hazardous Materials Management Plan (HMMP) is to provide information to the Poudre Fire Authority Fire Marshall regarding the New Belgium Brewing Company wastewater treatment plant storage area. The hazardous materials that will be used at this facility include sodium hydroxide and hydrochloric acid, which will be used to adjust the pH of the wastewater stream prior to biological treatment. In addition, bio-gas containing approximately 70% methane and 29% carbon dioxide will be generated and stored in a covered pond associated with wastewater treatment. This HMMP meets the requirements of Article 80 of the Uniform Fire Code, 1997 edition. This plan includes the following information: ➢ Storage and use areas of hazardous materials. ➢ Maximum amount of each material stored or used in each area. ➢ The range of the container sizes. ➢ Location of emergency isolation and mitigation valves and devices. ➢ Product -conveying piping that contains liquids or gases other than utility -owned fuel gas lines and low-pressure fuel gas lines. ➢ Storage plan showing the intended storage arrangement, including the location of aisles. 2.0 STORAGE AND USE AREAS OF HAZARDOUS MATERIALS The storage and use areas for the hazardous materials of the wastewater treatment area are shown on the attached Figures 1, 2 and 3. The bulk storage areas for the acid and caustic are completely separated by secondary containment areas with an approximate volume of 1,800 gallons each. The secondary containment areas will retain the entire volume of the largest tank plus 10 percent. The containment area is concrete and will be lined with an epoxy coating, which will protect the concrete from degradation by the acid or caustic material. 1470-006 (4) Hazardous Materials Management Plan Page 1 of 3 New Belgium Brewing Company Fort Collins, Colorado Stewart Environmental Consultants, Inc. 12 BUILDING SECTION A 3.1 3 +� o w C >. o3m Ld 4J W I Pd d d £ 3073 a Na-O L O d N L� d a a= L d a £ 0 L) L 3 W O LU £ N 3 0 O ON L) PO 3 L W O Z L_ N Legend U W -OCR mmvmt Imtol on velw O _"- Mw Vey OWCk Velw {' ¢ , m verr0 Urw e/ bell vdw I Y Z ® C wm* U4PlY Moto 0 RAP { ==,K'*%,Truck C O d (U L. � N CD 4 N L~ d +� AA M W L 3 O) L_ GAS—w—' w Ww --� W�— Trench drain and Spill Blo—Gas Storage Gate valve for Spill containment Volume 2000 rn�3 Pressure 1.5 atm POND Valve OPEN POND M E M U 0 0 0 04 LL. Lf) V) U') 0 C 0 z 7 LL- 1 LOWER 2, LEVEL Merud iodation Vdvr ae Way Urck vdvr Anti-uverM vent IYx W/ bail. vdw ® fhw&d SWWY W'arbV PUMP {Kam LO& fhift , Tr+,dc n 3 -P O rn +' in i O }' d d DI: 0)3 a ILA - o° Oj +, O d N L, d CL a= d a £ O U £ 3 N O LU PCII £ in 3 .9 0 NU i-' 3 L W O Z L. T d U N O O z 0 0 4. (U L- �% to _o >11�1 4 un 3 N L CS d +' A A A PRODUCT IDENTM: CAUSTIC SODA LIQUID 50% PAGES of6 EPA Registration number: Approved Product Uses: Special Notes: Not Amicable Not Appicable Nob: Deadly carbon monoxide gas can form when product contacts food soil containing sugars. After cleaning operations are oomplemd, thoroughly ventilate enclosed areas before entering. Always monitor oxygen and carbon mom" le" when personnel are in ericbsed areas. For proper lank entry procedures, see ANSI Z117-1-1977. NFPA 704 Health: 3 Fire: 0 Reactivity: 1 Special: MSDS Revision Information: Form Revision made 02,OgM4 Information Revised This Issue Data: MSDS distributed by Great Western Chemical Company Environmental Department Phone:800.547-1400 FAX:503-221-5767 Now MSDS formal with additional Womiatlon. June 09, 1994 This Material Safety Data Sheet is provided as an information resource only, it should rat be taken as a warranty or representation for which Great Western Chemical Company assumes legal responsibility. While Great Western Chemical Company believes the information contained herein is accurate and compiled from sources believed to be reffabfe• it is the responsibility of the user to investigate and verify its validity. The buyer assumes a1 responsibility of using and handling the product in accordance with applicable federal, state, and local regular". PRomm waffmR: CAUSTIC SODA LIQUID 50% PAGE S of 6 Components: Sodkm HydmWe MHA Tamid Omens: Eyes, Sian a Lungs Cwdnogsnb Potential: Regulated by OSHA: No Listed on NTP Report No IARC L'rstirug: No Rol"" Rq wthM CERCLA (40 CFR 302): Listed Substance: Yes Reportable Quantity: 1,000 Pounds Caugo7 C RCRA Waste No.: None fisted th listed Substance: Not applcabe ReRWA Quantity: Not applcable Charaotadsk Not applicable RCRA Waste No.: Not applicable SARA TITLE III Section 302 & 303 (40 CFR 355) Usted Substance: No ReP mis Omer.. Not applicable PkxMg Thtwtwid: Not applicable Section 31114 312 (40 CFR 370) Hazard Categories (product): Fla: N Sudden Relaws of Premn: N Reactive: N Aads Health: Y Chronic Health: N PlanningTtueahold: 10,000lbs. Section 313 (40 CFR 372) Listed Toxic Chemical: No Reporting Ttueshold: Not applicable U.S, TSCA STATUS Listed (40 CFR 710): Yes CANADIAN REGULATIONS Controlled Product: Yes WHMIS Hazard Symbols: Corrosive Material WHMIS Claw 3 Division: E Product Identification Number: UNIS24 10L Substance: Yes Domestic Subetance Ust: Yes CEPA Priority Ust: Not listed Carcinogenicity: ACGIH Appendix A: Not listed Al Confirmed Human: Not applicable At Suspeclad Human: Not spplaade IARC Group: Not listed STATE REGULATIONS: State of California Safe Drinking Water and Toxins Enforcement Act iwo (Proposition 65) Cercwrogen: No Reproductive Toxin: No OTHER REGULATIONS: hats RigtdTo Know Lawn: MA, NJ, PA PRODUCT IDENTIFIER CAUSTIC SODA LIQUID 50% PAGE 4 of 6 Eye CaM+ct: Stdn Contact: Oos Rat LDs: Dsmd Rabbit LDo: Waktion Rat lam: Human Data: 0tirrToxioo1o*W Diva: Cardnogenicky: Tsrstopankky: *Asgarbky: Synagistie Products: Target Organs: pH of water. Rabbit: 1 mW24 hours Severe Rabbit: 300 mg/24 hours Severe No data available No data available No data available No data available Oral Rabbit LDLo: 500 mg% No data available No data available Hameter,Luug: 10 mmol/L None reported Eyes, Skin & Lungs Skin or Respiratory diseases soluble in water. No specific environmental fate information available. This material will affect the ENVIRONMENTAL EFFECTS: Aquatic toxicity for this material is not available. RCRA 40 CFR 261 CLASSIFICATION: Corrosive Waste U.S. EPA WASTE NUMBER/DESCRIPTION: D002 If this product is disposed of as shipped, it meets the criteria of a hazardous waste as defined under 40 CFR 261 due to its corrosivity. If this product becomes a waste, it will be a hazardous waste which is subject to the Land Disposal Restrictions under 40 CFR 268 and mast be managed accordingly. As a hazardous liquid waste, it must be disposed of in accordance with local, state and federal regulations in a permitted hazardous waste treatment, storage and disposal facility by treatment. DOT PROPER SHIPPING NAME: Sodium Hydroxide solution DOT HAZARD CLASS: 8 UN NUMBER: UN1824 PACKING GROUP: II DOT LABELS: Primary: Corrosive Subsidiary: None Required DOT PLACARDS: Corrosive CERCLA Reportable Ouentity: 1,000 pounds (Nos . RO for product: 2,000 pounds (1572 gallons) MARINE POLLUTANT: No DOT Emergency Response Guidebook Number: 60 TDG PROPER SHIPPING NAME: Sodium Hydroxide, solution TDG HAZARD CLASS: 8(9.2) Regulated Urnit (RL): 50 kg (NaOH). Product: 100 kg (65.6 liters) UN NUMBER: UN1824 PACKING GROUP:. II TDG LABELS: Primary: Corrosive Subsidiary: None Required TDG PLACARDS: Corrosive . CANUTEC Initial Emergency Response Guide Number: 39 Other Shipping Information: None. PRODUCT EDENTHnFR: CAUSTIC SODA LIQUID 50% PAGE 3 of 6 ,�..iFrA F y r... �;r a' ti L< \ a x\ ♦ < - u a Y r - Ex > >2 xk \ :. } y . <T tiAiit?LN{�A41Q 1aiDFtA(3OWN$Ez,> ,� a .'\{':. STORAGE TEMPERATURE: Ambient STORAGE PRESSURE: Ambient GENERAL: Store in a cool, dry, well -ventilated area, away from incompatible material. Wear recommended personal protective equipment when handling material. Do not get material in eyes, on skin, or on clothing. Do not breathe mists. Use with adequate ventilation. Do not take internally. Material is corrosive to tin, aluminum, zinc and alloys containing these metals, and will read violently with these metals in powder form. Considerable heat is generated when material is mixed with water. Never add water to product. Always add material with constant stirring slowly to the surface of lukewarm (80° to 100° F.) water. If material is added too rapidly, or without stirring, and becomes concentrated at the bottom of mixing vessel, excessive heat may be generated, resulting in dangerous boiling and spattering, and a possible immediate and violent eruption of highly caustic solution. .r.............................t s t :: Sayr♦ t t L? t i{ < L i.tfr < < 2 r Z}r r 1 t� <\ 4, .0." AC, pF3�0' Gi'�QN.... .. M. y f r CONTROL MEASURES: Use local mechanical exhaust ventilation capable of maintaining emissions in the work area below the PEL or TLV. RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT: RESPIRATOR: For exposure above the PEL or TLV, wear a NIOSH-approved full facepiece or half mask air. purifying cartridge respirator equipped with a good particulate filter cartridge or supplied air. EYES: Wear chemical goggles (recommended by ANSI Z87.1-1979), unless a full fa epieoe respirator is worn. GLOVES: Neoprene, nitrite or rubber gloves. CLOTHING A Wear a neoprene, nitrite or rubber apron or full protective clothing when handling product. A eye EQUIPMENT: wash station and safety shower should be available in the work area. FOOTWEAR: Neoprene, nitrile or rubber boots. :...:..xf4. .....:'a.L. .:;;:oaf . ,........... _... °y Y�:i�4 o3 Y' �3 4 $;v.:w<?..n^.4;4li.vff^Avx:.:a,}.r„a.: rr{:Y (.;orr.\,: S..yw3.�:`['\ k;?) C:`;�^y..x;t:;?b°:' x. a<. x}�pj {.w {.'£4n F),.,. �> D 2h oo-§`Z > a r <�.< L �4< Orr _. 4... 4 ■1 /,({'day_ MA`..r:. Y* \ r3 0k\S SSG j'��i�i�/\IJ'MROf }.i"Myn?... ?�`r<•.. .�t,F.. {9.T•$)G A!IL Gfll�r1/��T' :'k .:�4n):..A:.:3{RFFf<}:.f Clear, to sWly turbid oolodess Bulk Not Physical State: Liquid Vapor Pressuro: 13 mm Hg @ 600 C. Odor. No characteristic Vapor Density *al): No data available Odor Threshold: No dada available Evamrafflon Rate Aatdtkt : No data available Molecular Formula: NaOH n wale() VOC Content: N1 Molecular Weight: 40.00 wale % Volatile: 49 to 51 Boilby Point: 1422' C. 880 F. Solubility in 0: Complete Frey U Point: 12Z C. 54° F. odenaiwater Partition Coefficient: No dada available Specific Gravity: 1.5253 20° C. PHas Is): 14.0 Density Wourda4anonr 12.72 pH (1% solution): 13.5 to 14.0 GENERAL: This product is stable and hazardous polymerization will not occur. CONDITIONS TO AVOID: Avoid contact with water. INCOMPATIBLE MATERIAL: Chlorinated and fluorinated hydrocarbons, acetaldehyde, acrulein, aluminum, . chlorine trifluoride, hydroquinone, maleic anhydride, phosphorous pentoxide, tetrahydrofuran and acids. HAZARDOUS DECOMPOSITION PRODUCTS: When heated to dryness and decomposition, it emits toxic oxides of sodium. SENSITIVITY TO MECHANICAL IMPACT: This product is not sensitive to mechanical impact. SENSITIVITY TO STATIC DISCHARGE: This product is not sensitive to static discharge. CONTINUED ON PAGE 4 PRODUCT IDENTIWR: CAUSTIC SODA LIQUID 50% PAGE 2 of 6 RyGti t ZA3'i'�liN3 #AEASt#AES : >f ..t y(. = t .t t ' iCf. INHALATION: If inhaled, immediately move to fresh air. If not breathing, give artificial respiration, using the Bolger Nielsen method (back pressure -arm lift). Do not use mouth-to-mouth method if victim has ingested or' N inhaled the substance. If breathing is diflicult, give oxygen. Call a physician. EYE CONTACT: In case of contact, immediately flush eyes with plenty of clean running water for at least 15 minutes, lilting the upper and lower lids occasionally. Remove contact lenses, if worn. Get medical attention immediately. SKIN CONTACT: In case of contact, immediately flush skin with plenty of clean running water for at least 15 minutes, while removing contaminated clothing and shoes. If burn or irritation occurs, call a physician. INGESTION: If swallowed, DO NOT induce vomiting. Get medical attention immediately. If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person. NOTE TO PHYSICIANS: Sodium hydroxide solutions have a low oral toxicity, but may be corrosive to the eyes, skin and mucous membranes. Consideration should be given to careful endoscopy as stomach or esophagel burns, perforations or strictures may occur. Careful gastric lavage with an endotracheal tube in lace should be considered. Treat ex re tomaticall . ..>7 xR:#lltiw..VTl �li`♦�'3►IFC1S4i�'1 yyy ...i L } j xYi y i k .y f Flashpoint and Method: Not applirable Flammable Units (feet,%brrebss): Lower: Not applicable Upper: Not applicable Autolgrddon Temperature-. Not applcable GENERAL HAZARD: Material is a non-combustible aqueous solution. Direct contact with water may cause a violent exothermic' reaction. Diluted solutions of this material may be corrosive and may evolve flammable/explosive hydrogen gas on contact with most metals. May produce hazardous fumes or hazardous decomposition products. FIRE FIGHTING INSTRUCTIONS: EXTINGUISING MEDIA: Foam, COY or dry chemicals. Do not use water spray or fog directly on material. This material may react violently with water to release heat. FIRE FIGHTING EQUIPMENT: Fire fighters should wear full protective equipment, including self-contained breathing apparatus. HAZARDOUS COMBUSTION PRODUCTS: When heated to dryness and.decompoeition, "material emits toxic fumes of sodium oxides. E:CIC1EIiTA[,REA�E MBA$tlRE$, LAND SPILL: Wearing recommended protective clothing, dike spill using soil, sand or compatible commercial absorbent. Pick up bulk of liquid using pumps or vacuum truck or absorb liquid in sand or commercial absorbent. Place liquid in approved containers for recovery or disposal. Neutralize remaining traces of material with any dilute inorganic acid, such as hydrochloric, sulfuric, nitric, etc. The spill area should then be flushed with water, followed by a liberal covering of sodium bicarbonate. Collect riasates and containerize for disposal. Prevent run-off from contaminating sewers, streams or other bodies of water. WATER SPILL: This solution is heavier than water and is completely soluble in water. Stop or divert water flow. Dike contaminated water and remove for disposal and/or treatment. Notify all downstream users of possible contamination. CONTINUED ON PAGE 3 MATERIAL SAFETY DATA SHEET GW) GREAT WESTERN CHEMICAL COMPANY t:tSWE DATE: 06/09/64 I SUPERSEDES: 01/22/93 I GREAT WESTERN MSDS NUMBER: 46172 NFPA 704 DESIGNATION /\Fire HAZARD RATING ! e 4 a Extreme 3 1 3 . High Health Ra 2 - Moderate 1 . SfiQht 0 . Insrgnificartc SPedal N4'f.:ttny:,••.� :..%vY': f:3:ifi>• <43Y:}/... ..k i� i}}i :4': Y'.YY'v: wt�: :.•v4.: v..:£....i..tik:..:i.imY.tN;<:is4i�::v:Fk:3R:$'v4.:3'}"',:Y.4 .Y:>:.....4'.}}:v'.}ri::'}:41'. .:�:'f:�.t�.:\[Y].rrin::i... .. iY:ft4 :: 3 >.s>:. t : �:+?<..�r:.',.i%Ik. Y3, t PRODUCT IDENTIFIER: CAUSTIC SODA LIQUID N-M GENERAL USE: Used in industry to neutralize adds; to precipitate alkaloids; in metal finishing; in cleaners;and to precipitate most metals (as hydroxides) from aqueous solutions. PRODUCT DESCRIPTION: An aqueous solution of sodium hydroxide. Synonyms for sodium hydroxide include: caustic soda, lye, soda Nye, sodium hydrate, and white caustic. INFORMATION PROVIDED BY. GREAT WESTERN CHEMICAL COMPANY CaWaig Office£F[ ftGQ�lGfP,.:.QNENUMBF at[':.>f„ 8W S.W. I51h Avenue GREAT WESTERN: 800-GWSPILL Pordard, OR 07206 CHEMTREC: 800.424-9300 PHONE 503-228-M FAX 503-221 5767 CANUTEC 612 996a% 2 b h-. t} .} t } { ` Y t t { ) 4; CCyMPD$[TtON B WFQRMATIONQNiIVGREIkIl=P1TS k > 3 it ACGIH OSHA COMPONENT CA$# OSHA HAZARD Wt.% TLYrtwu STEL PEL(twp STEL Sodium Hydroxide 001310-73-2 Corrosive, Lung toxin 50 ± 1 None No None None Ceiling 2 mg/m Ceiling: 2 mg/m .HAZARD$ ICfE1VT1FlCATiQ[ ;XX EMERGENCY OVERVIEW: A clear, to slightly turbid, colorless liquid with no characteristic odor. Liquid and mists are corrosive to all tissues contacted. Inhalation of mist can cause permanent lung damage. Material may react violently with water, acids and other substances. POTENTIAL HEALTH EFFECTS: INHALATION: Inhalation of mists maybe severely irritating or corrosive to the nose, mouth, throat and lungs. Exposure may cause burns to the respiratory tract with the production of lung edema which can result in shortness of breath, sneezing, choking, chest pain and impairment of lung function. Inhalation of high concentrations may result in permanent lung damage. EYE CONTACT: Exposure to liquid or mists can cause severe irritation and/or burns, with symptoms of tearing, redness, _swelling and pain. Corneal damage with impairment of vision may result from direct contact with liquid. SKIN CONTACT: Exposure to liquid or mists can cause severe irritation and/or burns characterized by redness, swelling and scab formation. Prolonged skin exposure to liquid may cause destruction of the dermis with impairment of the skin at site of contact to regenerate. No published data indicates material is absorbed through the skin. INGESTION: Ingestion can cause severe irritation and/or burns to the entire gastrointestinal tract, including the stomach and intestines, characterized b3, nausea, vomiting, diarrhea, abdominal pain, bleeding and/or tissue ulceration. CHRONIC: The chronic health effects of exposure to liquid or mists would be the same as for acute exposure. CONTMTP.T) 0H PACF 9 •«• SECTION 10 - ADDITIONAL INFORMATION .... Additional Information: No additional information available. MSDS Creation Date: 1/09/1995 Revision #14 Date: 9/02/1997 The information above Is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such Information and we assume no liability resulting from Its use. Users should make thafr own Investigations to determine the suitability of the Information for their particular purposes. In no way shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special. Indirect, incidental, consequential or exemplary damages, howsoever arising, even If Fisher has been advised of the possibility of such damages. _____________________________________________________________________ PAGE 1; DATE: 12/19/97 ACCT: 244110001 INDEX: H73524724 CAT;NOs A144212 �10 NSN. 194,7 ,.. **** MATERIAL SAFETY DATA SHEET **** Hyydrochloric Acid 11155 **** SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION *••* MSDS Name: Hydrochloric Acid Catalog Numbers: 144J212, A142 212. A142-212, A142212, A142P 20, As A144 500. A144 500L8, A144 612GAL, A144-20, A144- A144-5001.11. A144-612G. A144-612GAL, A144-612GL, A144500LB02. A144500LDLC. A1445212LC, A144612GA A144C-212. A144C212, A144C212001, A144FP 500, At, A144P 500. A144P-1GA, A144P-IGAL, A144P-20. A144 A144S 500. A144S-212. A144S-500, A144S212. A144S! Synonyms: Chlorohydric acid. hydrogen chloride, muriatic acid, spirits of salt. Company Identification: Fisher Scientific 1 Reagent Lane Fairlawn, NJ 07410 For information, call: 201-796-7100 Emergency Number: 201-796-7100 For CH EMTREC assistance, call: 800-424-9300 For International CHEMTREC assistance. call: 703-527-3887 **** SECTION 2 - COMPOSITION. INFORMATION ON INGREDIENTS **** ----------------- ----------------------------------------------------- CAS# Chemical Name % EINECS# ------------------------------------------------------ ---------- ___ 7647-01-0 Hydrogen chloride 36-38% 231-595-7 ----7732-18-5 Water--------------------------62-64% 231-791-2 --- -- _______________________________________________________ Hazard Symbols: C **** SECTION 3 - HAZARDS IDENTIFICATION **** EMERGENCY OVERVIEW Appearance: cleagcolorless. Danger! Corrosive. Sensitizer. Causes eye and skin burns. May cause severe respiratory and digestive tract irritation with possible burns. Target Organs: None. Potential Health Effects Eye: May cause irreversible eye in7'ury. Vapor or mist may Cause irritation and severe burns. Contact with liquid is corrosive o the eyes and causes severe burns. May cause painful sensitization to light. May cause conjunctivitis. Skin: May be absorbed through the skin in harmful amounts. Cancan with liquid is corrosive and causes severe burns and ulceration. May cause photosensitization in certain individuals. Ingestion: May cause circulatory system failure. Causes severe digestive tract burns with abdominal pain, vomiting, and possible death. May cause corrosion and permanent tissue destruction of the esophagus and digestive tract. Inhalation: Causes severe irritation of upper respiratory tract with toughing, burns, breathing difficulty, and possible coma. May cause pulmonary edema and severe respiratory disturbances. Chronic: Prolongedor repeated skin contact may cause dermatitis. Repeated exposure may cause erosion of teeth. May cause conjunctivitis and photosensitization. **** SECTION 4 - FIRST AID MEASURES **** Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Skin: Get medical aid. Rinse area with large amounts of water for at least 15 minutes. Remove contaminated clothing and shoes. Ingestion: Do NOT induce vomiting. If victim is conscious and alert. give 2-4 FAGk* 2 ".OATEs 12�i9i97 ACL7i 744iO0Q1 :INOEXs if73$24724. t'At: NOx A214P22 ...APO 316k7 cupfuls of milk or water. Get medical aid immediately. Inhalation: Remove from exposure to fresh air immediately. If not breathing, alve artificial respiration. If breathing is difficult, give oxygen. at medical aid. Notes to Physician: Treat symptomatically and supportively. Antidote: No specific antidote exists. **** SECTION 5 - FIRE FIGHTING MEASURES •*•• General Information: As In any fire, wear a self-contained breathing apparatus in pressure -demand MSHA/NIOSH (approved or equivalent), and full protective gear. Not flammable, but reacts with most metals to form flammable hydrogen gas. Use water spray to keep fire -exposed containers cool. Extinguishing Media: Substance is nonflammable; use agent most appropriate to extinguish surrounding fire. Au t osgnition Temperature: Not available. Flash Point: Not available. NFPA Rating: Not published. Explosion Limits, Lower. Not available. Upper: Not available. +*+* SECTION 6 - ACCIDENTAL RELEASE MEASURES •••* General Information: Use provper personal protective equipment as indicated In Section b. Spills/Looks: Larga spills may be neutralized with dilute alkaline solutions of soda ash, or lime. Absorb spill using an absorbent, non-combustible material such as earth, sand, or vermiculite. •*** SECTION 7 - HANDLING and STORAGE **** Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get on skin or in eyes. Do not Ingest or inhale. Storeg8: Keep away from heal and flame. Do not store. in direct sunlight. Store In a cool, dry, well -ventilated area away from Incompatible substances. •*** SECTION 8 - EXPOSURE CONTROLS. PERSONAL PROTECTION ***+ Engineering Controls: Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Exposure Limits ____________________♦--__---_--_-___-_---_______________-___-________________-* Chemical Name ACGIH NIOSH OSHA - Final PELs ____________________ ___________________ ___________________ _________________ Hydrogen chloride C 5 ppm; C 7.5 C 5 ppm; C 7 C 5 ppm; C 7 ri3 m9/m3 mg/m3 Water none listed none listed none listed t____________________t___________________t________________-_-*____---_-__------* OSHA Vacated PELs: Hydrogen chloride: C 5 ppm; C 7 mg/ni Water: No OSHA Vacated PELs are listed for this chemical. Personal Protective Equipment Eyes: Wear a?age a a protective eyeglasses or chemical protection eregulationscInb29 by 19i10-1331.e and face Skin: Wear appropriate protective gloves to prevent skin Clothing: exposure. Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found In necessary Always use a NIOSM-approved respiratoror when necessary. •••* SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES •••• Physical State: Liquid Figures Stewart Environmental Consultants, Inc. Attachment A Material Safety Data Sheets Stewart Environmental Consultants, Inc. 6.0 PRODUCT -CONVEYING PIPING The product -conveying piping is shown on the drawings. The piping diagram shows the location of the unloading area and the piping connected to the storage tanks. The location of the bio-gas lines and isolation valves are also shown. 7.0 ON -OFF VALVE POSITIONS The Off -On positions of the valves will be noted on the valves. Training will be provided for personnel operating the wastewater system as part of the hazardous materials training program. New Belgium will also label all hazardous materials piping with labels that meet the UFC code. 8.0 HAZARDOUS MATERIALS STORAGE LOCATIONS The storage areas are shown on the Figures. This storage plan indicates the following: 1. The proposed location of the storage tanks. 2. The secondary containment around the storage tanks. 3. The unloading area for these hazardous chemicals. Note that the unloading area also contains a secondary spill containment area that contains the entire volume of a tanker truck plus 10 percent. This will contain any spill and additional storage from a precipitation event, if present. As part of this submittal, we have provided in Attachment A the Material Safety Data Sheets for this project. Note that the proposed chemicals in the bulk storage tanks are of the concentration listed on the MSDS. 1470-006 (4) Hazardous Materials Management Plan Page 3 of 3 New Belgium Brewing Company Fort Collins, Colorado Stewart Environmental Consultants, Inc. 3.0 MAXIMUM AMOUNT OF MATERIAL STORED OR USED IN EACH AREA The maximum amount of acid and caustic material to be stored is provided in Table 1, which exceeds the exempt amounts allowed in the code. These storage amounts will require an H 1 rating for the construction of this building. Due to the acidic and caustic nature of the materials, New Belgium is requesting that a sprinkler system not be utilized in this facility. An accidental discharge of water into this area could cause an emergency and could endanger the personnel within the building. The volume of bio-gas to be stored is also shown in Table 1. Hazardous Material Minimum Storage Maximum Storage Hydrochloric Acid (HCl) 200 gallons 1,200 gallons Caustic Soda (NaOH) 200 gallons 1,200 gallons Bio-gas (70% CH, and 29% COZ) 2,000 m3 2,000 m3 4.0 RANGE OF CONTAINER SIZES The two containers that store hydrochloric acid and caustic soda are 1,500 gallons each. The only other chemical that could potentially be on site is ferric chloride (FeCl3) which is typically stored in a dry form (50 pound bags) and then mixed in a day tank. The size of the day tank is approximately 50 gallons. 5.0 LOCATION OF ISOLATION VALVES AND DEVICES The locations of the isolation valves are provided on the Figures. Isolation valves are located in the bulk unloading area as well as at each chemical storage tank. Each tank also has a valve that prevents overfilling as noted on the plans and as required by the UFC. The bio-gas line also has isolation valves at various locations as shown on the Figures. 1470-006 (4) Hazardous Materials Management Plan Page 2 of 3 New Belgium Brewing Company Fort Collins, Colorado Stewart Environmental Consultants, Inc. STEWART ENVIRONMENTAL CONSULTANTS, INC. 'K" Consulting Engineers and Scientists May 15, 2001 Mr. Kevin Wilson Fire Marshall Poudre Fire Authority 102 Remington Fort Collins, CO 80524 Office & Laboratory: 3801 Automation Way, Suite 200 Fort Collins, Colorado 80525 (970) 226-5500 FAX (970) 226-4946 stewart@webaccess.net Subject: New Belgium Brewing Company — Hazardous Materials Management Plan Job No.: 1470-006 (4) Dear Mr. Wilson: Attached is the New Belgium Brewing Company — Wastewater Treatment Facility Hazardous Materials Management Plan. This plan includes the information required under Article 80 of the Uniform Fire Code, 1997 edition. Please review this plan as part of the brewery submittal for planning. If you require any additional information, please contact me at 226-5500. We appreciate the cooperation and assistance we have received from Poudre Fire Authority regarding this submittal. Sincerely, STEWART ENVIRONMENTAL CONSULTANTS, INC. Dr. David R. Stewart, PE President & CEO cc: Fred Porter, New Belgium Brewing Company 1470-006 (4)\haz mat man plan 15may01 "rpt