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HomeMy WebLinkAboutNEW BELGIUM BREWERY, 2ND FILING - PDP / FDP - 1-95B - SUBMITTAL DOCUMENTS - ROUND 1 - HAZMATSArchistruction' July 8, 1997 Ted Sheppard Planner City of Fort Collins 281 North College Avenue Fort Collins, CO 80522-0580 Re: New Belgium Brewery Hazardous Materials Analysis Dear Ted: Fort Collins P.O. Box 2127 (80522) 2620 E. Prospect Rd. Suite 100 Ft. Collins, CO 80525 (970) 493-8747 (970) 493-5869 FAX Denver Eighteenth Street Atrium 1621 18th Street, Suite 250 Denver, CO 80202 (303)296-0383 (303) 296-0382 FAX Colorado Springs P.O. Box 1478 Colorado Springs, CO 80901-0182 (719) 633-4713 I have attached MSDS sheets for all hazardous materials used at New Belgium Brewery. All products listed are used for cleaning and sterilization in the food products industry and are used in diluted quantities. Sincerel K. Merl Haworth Architect KMH/pi enc. GW GREAT WESTERN CHEMICAL CO. 5700 N.W. Front Ave. Portland, Oregon 97210 (503) 227-1616 SANICHEM Product Information Bulletin LCA - 619 LIQUID CAUSTIC ADDITIVE DESCRIPTION: LCA - 619 is a concentrated liquid additive for use in caustic solutions. LCA - 619 is designed to supply wetting action, mineral sequestration, provide some anti -corrosion properties, and aid rinsability in the food processing industry. FEATURES AND BENEFPTS: RINSES FREELY - helps prevent caustic filming on equipment surfaces and allows faster rinsing of caustic solutions. POWERFUL WETTING PROPERTIES - provides penetrating action on soiled surfaces. CHELATED - sequesters and chelates troublesome minerals and metals. HEAT STABLE - for evaporators, H.T.S.T. units, fryers, blanchers, ultra high temperature equipment, etc. ECONOMICAL - mixes readily and is easy and economical to use. VERSATILE - can be added to build shipments of caustic or injected separately in an automatic CIP system. COLD TEMPERATURE STABILIZED - will not salt out at lower temperatures. TYPICAL PROPERTIES: Appearance ................. Clear, brown liquid Alkalinity as Na2O to pH 4.3 ..... 0.3% Causticity as Na2O to pH 8.3 ..... 0.0% Specific Gravity @ 20 °C 1.208 pH of (as is) Solution 7.5 - 9.5 Density 10.1 1bs/gal Foaming Characteristics ..... Low RECOMMENDED USES: LCA - 619 is recommended for any application where caustic is used for cleaning. Recommended for cold and hot CIP pipelines, H.T.S.T. units, evaporators, brew kettles and kegs, cookers, fryers, blanchers, fillers, and general food processing equipment. Improves caustic performance on most food soils in varying water conditions. FIVE STAR AFFILIATES Five Star Products R Services LLC. Five Star Food Grade L.L.C. Five Star Packaging & Equipment LLC. Five Star Corporation ,Suppliers of Spociany Clooning Compounds 6 Equipment Since 1980' QUANTUM BENEFITS 1. Broad Spectrum of Bacterial Control 2. Low in Odor 3. No Rinse RequiredWhen Used at 200 ppm 4. Accepted by U.S.D.A_ in all departments. DESCRIPTION 6731 East 50th Avenue Commerce City, CO 80022 (303) 287-0186 • (800) 631. 3601 Fax (303) 287-0391 QUANTUM is designed specifically for hospitals, food processing plants, dairies, restaurants, bars, animal quarters, kennels, and institutions where disinfection, sanitization and deororizations is of prime importance. QUANTUM will sanitize previously cleaned and rinsed non -porous food contact surfaces such as tanks, chopping blocks, counter tops, drinking glasses, and eating utensils. QUANTUM can also be used to sanitize previously cleaned food grade egg and egg product processing plants. PROPERTIES APPEARANCE ................................... CLEAR WATER WHITE ODOR................................................MILD TO SWEET pH of CONCENTRATE ............................................ 7 to 8. SPECIFIC GRAVITY...........................:..................0.994 GENERAL USE DIRECTIONS 71 For most sanitizing applications use QUANTUM at 1 ounce per 4 gallons of water to produce. a 200 ppm solution. This solution does not require a potable water rinse. Follow label directions for variations in sanitizing procedures. COMPLIANCE QUANTUM is acceptable to the U.S. Department of Agriculture for use as a general cleaning agent in official meat, poultry, rabbit, and egg processing establishments. After use surfaces must be rinsed with potable water. The only exception is the 200 ppm solution. CAUTION: Can be harmful is swallowed. Can cause eye irritation. This product contains surfactants. For eye contact, flush thoroughly with cool running water for 15 minutes. Get medical attention. If swallowed drunk large amount of water or milk. Call a physician. Wash after use. DO NOT induce vomiting. The text above is given for information only. Five Star Products and Services makes no warranties, either expressed or implied, concerning the use of this product other than for the purpose indicated. page ACID No. 5 SPECIAL PROTECTION INFORMATION PROTECTIVE GLOVE: Recommended (rubber, PVC) EYE PROTECTION: Recommended (goggles, full face shield) RESPIRATORY: Not required normaly LOCAL EXAUST: Recommended ventilated area OTHER EQUIPMENTs. Recommended to protect skin, use rubber boots, apron, and sleeve protectors REACTIVITY DATA INCOMPATIBLE MATERIALS: Alkalies, chlorinated products, soft metals, ammonia STABILITY: Product is stable POLYMERIZATION: Will not occur DECOMPOSITION PRODUCTS: May give off phosphorous or nitrous oxide at high heat (fire conditions) 0 SPILL OR LEAK PROCEDURES SPILL: Wearing saftey equipment dike the liquid and recover into drum, if possible.. Neutralize residue with soda ash and flush to sewer if permitted. Waste product is an EPA Hazardous Waste (DO02) due to corrosivity. Comply with all local, state, and federal regulations PREPARED BY: c EMERGENCY CONTACT:- CHEMTEC E 0-422 -93(--)!l MATERIAL SAFETY DATA SHEET ACID CLEANER No. 5 FIVE STAR CORPORATION PHONE: (8(.11) 265-2468 P.O.BOX 26488 MSDS DATE: 8/20/90 SALT LAI::E CITY, UT 84127 REPLACES: 12/05/85 IDENTIFICATION PRODUCT NAME: ACID CLEANER No. 5 COMPOSITION: MIXTURE OF PHOSPHORIC AND NITRIC ACIDS ------------------------------------------------------------ HAZARDOUS INGREDIENTS: % TLV LIMITS IN AIR Phosphoric Acid (CAS 7664-38-2) 8 1 mg/m3 (ACGIH) Nitric Acid (CAS 7697-37-2) 38 2 ppm (ACGIH) PHYSICAL DATA APPEARANCE: Dark: Blue Liquid ODOR: Acidic SOLUBILITY IN WATER: Complete SPECIFIC GRAVITY: 1.16 EVAPORATION RATE: 1 (water=l) E40ILING POINT: 220 F VAPOR PRESSURE: 24 mm. Hg. pH of concentrate: 1.4 FIRE & EXPLOSION DATA FLAMMABLITY: Not flammable EXTINGUISHING MEDIA: Water, Carbon Dioxide, Foam UNUSUAL FIRE AND May emit toxic fumes of nitrous or EXPLOSION HAZARDS: phosphorous oxide with high heat HEALTH HAZARD DATA EYE EFFECT: Corrosive to eye Sl::I N EFFECT: Corrosive to skin INGESTION: Corrosive to gastrointestinal tract INHALATION: Can cause irritation or burns EMERGENCY & FIRST AID PROCEDURES EYE CONTACT: Flush with cool running water .for at least 15 minutes. Get medical attention. SY:IN CONTACT: Flush with cool water, if irritation develops get medical attention. INGESTION: If conscious, give several glasses of milk, water, egg whites, or gelatin solution. Get medical attention immediately. DO NOT induce vomiting. INHALATION: Get to fresh air. page ACID No. 1 get medical attention. INGESTION: If conscious, give several glasses of milk, water, egg whites, or gelatin solution. Get Medical attention immediately. DO NOT induce vomiting. INHALATION: Get to fresh air. SPECIAL PROTECTION INFORMATION PROTECTIVE GLOVES: Recommended (rubber, PVC) EYE PROTECTION: Recommended (goggles, full face shield) RESPIRATORY: Not required normaly LOCAL EXAUST: Recommended OTHER EQUIPMENT: Recommended to protect skin, use rubber boots, apron, and sleeve protectors. REACTIVITY DATA INCOMPATIBLE MATERIALS: STABILITY: POLYMERIZATION: DECOMPOSITION PRODUCTS: Alkalies, chlorinated products, soft metals, organic compounds Product is stable Will not occur May give off phosphorous and nitrous oxide at high heat (fire conditions) SPILL AND DISPOSAL SPILL: Wear safety equipment. Dike the liquid, neutralize, and recover into drums. Flush the residue to the.' sewer with large amounts of water. Flush small spills to the sewer with large amounts of water. DISPOSAL: Material collected in drums is an EPA hazardous waste (DO02) corrosive. Dispose of it in an EPA approved facility. Comply with all federal, state, and local regulations. PREPARED BY: 0 1n°-� jam^ "� Emergency contact: INFOTEC i-BOO-535-5053 MATERIAL SAFETY DATA SHEET ACID CLEANER No. 1 FIVE STAR. CORPORATION PHONE: (303) 287-0186 6731 EAST 50TH AVENUE MSDS DATE: 04/10/92 COMMERCE CITY, CO 80022 REPLACES: 08/10/90 IDENTIFICATION PRODUCT NAME: ACID CLEANER NO. 1 COMPOSITION: MIXTURE OF PHOSPHORIC AND NITRIC ACID ----------------------=------------------------------------- This product requires submission of an anual report on the release of toxic chemicals that appear in 40 CFR 372 (for SARA 313). Components present in this product at a level which could require reporting under the statute are: ------------------------------- HAZARDOUS INGREDIENTS: Phosphoric Acid (CAS 7664-38-2) Nitric Acid (CAS 7697-37-2) ------------------------- % TLV LIMITS IN AIR 30 1 mg/m3 (ACGIH) 30 2ppm (ACGIH) PHYSICAL DATA APPEARANCE: Dark. Blue Liquid SOLUBILITY IN WATER: Complete EVAPORATION RATE: 1 (water=1) VAPOR PRESSURE: 24 mm. Hg. ODOR: Acidic SPECIFIC GRAVITY: 1.25 BOILING POINT: 213 F pH of CONCENTRATE: 1.2 FIRE & EXPLOSION DATA FLAMMABILITY: EXTINGUISHING MEDIA: UNUSUAL FIRE AND EXPLOSION HAZARDS: EYE EFFECT: SKIN EFFECT: INGESTION: INHALATION: Not flammable Water, Carbon Dioxide, Foam May emit toxic fumes of nitrous phosphorous oxide with high heat HEALTH HAZARD DATA Corrosive to eye Corrosive to skin Corrosive to gastrointestinal tract Can cause irritation or burns EMERGENCY & FIRST AID PROCEDURES EYE CONTACT: Flush with cool running water for at least 15 minutes. Get medical attention. SKIN CONTACT: Flush with cool water, if irritation develops,., COMPLIANCE STAR SUPER CIP is acceptable to the U. S. Department of Agriculture for use in official meat, poultry, rabbit, and egg processing establishments. After use, surfaces must be rinsed with potable water. AFETY WARNING: Can cause burns to skin and eyes. Harmful or fatal if swallowed. Contains Caustic Soda and Sodium Dichloro-s-Triezinetrone. Avoid contact with skin and eyes. DO NOT get on clothing. Avoid breathing dust. Use a respirator when handling. DO NOT take internally. DO NOT mix with acid or a violent reaction may occur foaming Chlorine Gas. FIVE STAR AFFILIATES Five Star Products 6 Services LLC. Five Star Food Grade L.L.C. Five Star Packaging 6 Equipment LLC. Five Star Corporation 'Suppliers of Specialty Cleaning Compounds d Equipment Since 1980- STAR SUPER CIP EFITS 1. Highly Concentrated Chlorinated Caustic Cleaner 2. Effectively Removes protein Staining 3. Low Foaming Surfactant for Quick Soil Penetration 4. U.S.D.A. accepted in all areas. DESCRIPTION 6731 East 50th Avenue Commerce City. CO W022 (303) 287-0186 • (8t10) 631.8601 Fax (303)287.0391 STAR SUPER CIP is a highly chlorinated caustic cleaner for the food and dairy industries. It is resigned to be a low foaming CIP cleaner that will effectively remove protein soils as will as dairy fats at low concentrations. The amount of chlorine in this product will control the bluing found on stainless steel after heat processsing of protein based products. APPEARANCE ....................................WHITE GRANULAR ODOR ..........................................CHLORINE TYPICAL FOAM.........................................................LOW % AVAILABLE CHLORINE ............................. 1.75 MINIMUM TOTAL ALKALINITY .................................. 30.0 MINIMUM GENERAL USE DIRECTIONS Immediately after processing rinse all equipment thoroughly. Make up a CIP solution at a rate of 1 pound of STAR SUPER CIP per every 15 - 30 gallons of water. The concentration will depend on the soil type and the load amount in the equipment. Circulate at normal CIP temperatures. Page 3 STAR SAN SPECIAL INFORMATION STORAGE PRECAUTIONS: Corrosive liquid. Do not store near heat or open flame. Avoid contaminations of food or feedstuffs. Keep container closed when not in use. Do not store below 0 ° F or above 100 ° F for extended periods. DISPOSAL: Do not reuse containers. Triple rinse, puncture and dispose of containers in a sanitary landfill or by incineration. Wastes resulting from use of this product may be disposed of on site or at an approved waste disposal facility. facility. Prepared by:� 1;111'It(,ENCI' TI%LEPIIONE: INFOTRAC 800-535-5053 MATERIAL SAFETY DATA SKEET FIVE STAR AFFILIATES, INC. PHONE: 303-287-0186 6731 E. 50TH AVENUE MSDS DATE:7-1-92 COMMERCE CITY, CO. 80022 REPLACES:11-13-90 IDENTIFICATION PRODUCT NAME: STAR SAN COMPOSITION: Solution of Phosphoric Acid and Dodecylbenzene sulfonic acid. IIALARDOUS INGREDIENTS: Phosphoric Acid Dodecylbenzene Sulfonic Acid % ACG1H TLV 50.0 1 mg/ In 15.0 N/A (Other compositional information is considered a trade secret). PHYSICAL DATA APPEARANCE: Greenish to amber liquid SOLUBILITY IN WATER: Complete ODOR: Alcohol SPECIFIC GRAVITY: 1.32 @ 60 °F FIRE AND EXPLOSION DATA FLAMMABLITY: Flammable FLASH POINT: 133 F (T.C.C.) EXTINGUISHING MEDIA: Water or Carbon Dioxide UNUSUAL FIRE & EXPLOSION HAZARDS: Moderate explosion hazard if exposed to heat and flames. May emit toxic fumes of sulfur oxides and phosphorous oxide with high heat. BEALTH HAZARD DATA CORROSIVE LIQUID: Causes eye and skin damage. Harmful if swallowed. PRIMARY ROUTE OF ENTRY: Accidental ingestion. EFFECTS OF OVEREXPOSURE: Eye and lung irritation, may be fatal due to burns to the gastrointestinal tract. MATERIAL SAFETY DATA SHEET FIVE STAR AFFILIATES, INC. 6731 E. 50TH AVENUE COMMERCE CITY, CO. 80022 IDENTIFICATION PRODUCT NAME: LIQUID CIRCULATION CLEANER i#1 COMPOSITION: CAUSTIC SODA AND CHELATORS PHONE: 303-287-0186 MSDS DATE: 2-20-92 REPLACES: 11-13-90 This product requires submission of an annual report on the release of toxic chemicals that appear in 40 CFR 372 (for SARA 313). Components present in this product at a level with could require reporting under the statute are: HAZARDOUS INGREDIENTS: Caustic Soda (CAS 1310-73-2) PHYSICAL DATA APPEARANCE: Light Amber liquid SOLUBILITY IN WATER: Complete EVAPORATION RATE: 1 (water --I) VAPOR PRESSURE: 24 mg.Hg. % TLV LIMIT IN AIR 44 2 mg/m3 (ACGIH) 2 mg/m3 (OSHA) ODOR: Odorless SPECIFIC GRAVITY: 1.49 BOILING POINT: 220 OF. pH CONCENTRATE: 13.3 FIRE AND EXPLOSION DATA FLAMMABILITY: Not flammable EXTINGUISHING MEDIA: Water, Carbon Dioxide, Foam UNUSUAL FIRE AND EXPLOSION HAZARDS: None HEALTH HAZARD DATA EYE EFFECT: Severe burns, can cause permanent damage or blindness. SKIN EFFECT: Severe burns, corrosive. INGESTION: Can cause severe burns to gastrointestinal tract which could result in death. ORAL: LD50 rat = 140-340 mg/Kg. DERMAL: LD50 rat = 1350 mg/Kg. C PRODUCTNAME,LCA-619 CHRONIC EXPOSURE EFFECTS STABILITY UNSTABLE STABLE INCOMPATIBILITY (materials to avoid) ` PAGE 3 of 4 Repeated. exposure may ."lead to'dermatitis; otherwise, same as for overexposure. V. REACTIVITY DATA CONDmONS None TO AVOID Strong oxidizers HAZARDOUS When heated to decomposition, it emits toxic oxides DECOMPOSmONPRODUCTS of carbon, phosphorus and sodium. HAZARDOUS POLYMERIZATION CONDITIONS MAY OCCUR WILL NOT OCCUR X TO AVOID None VI. SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN Contains filled liquid. IF MATERIAL IS P q (For small spi 11 s, add dry material to RELEASED OR SPILLED contain.) Wearing recommended protective equipment, remove bulk of liquid. Add dry material to absorb remaining liquid; pick up and containerize for recovery or disposal. Flush area with water to remove residues. WASTE DISPOSAL METHOD This product, if disposed as shipped, is not a hazardous waste as specified in 40 CFR 261. Consult state or local officials for proper disposal method. When empty, thoroughly rinse container with water before disposal, return to manufacturer, or any other industrial use. L MATERIAL SAFETY NFPA 704 DESIGNATION DATA SHEET- ;-•.NAZARDRATING CHENLAXI4 = Extreme Hs�roi 2 3 = High ` 2 = Moderate 1 = Slight Issue Date: 08/31/93 Supersedes: 07/13/93 0 = Insignificant PRODUCT NAME LCA-619 CHEMICAL NAME: N/A CHEMICAL FAMILY: Caustic Additive FORMULA: Proprietary MOLECULAR WEIGHT N/A D.O.T. SHIPPING CLASSIFICATION: Not Restricted I. PHYSICAL DATA BOILIN760mm, H POINT g > 2120 F. (1000 C.) FREEZING o 0 < 32 F. (0 C. ) POINT SPECIFIC GRAVITY (WATER = 1) 1.196 @ 200 C. pH of1%(w/v) 3.9 - 4.5 SOLUTION PERCENT VOLATILE ORGANICS BY VOLUME N/A SOLUBILITY Complete IN WATER Clear, yellow to amber liquid with a surfactant odor. APPEARANCE AND ODOR _ If. HAZARDOUS INGREDIENTS MATERIAL HAZARD °ktVt I ACGIH TLV (Units) OSHA PEL This product is not manufacture to contain a hazardous componen as defined in the following regula ions 49 CFR 172 and 29 CFR 1910. All chemicals contained in this Control Act (TSCA) Inventory. product are listed on the Toxic Substance N/A = Not applicable; NDA = No ata Available If. HAZARDOUS INGREDIENTS Great Western Chemical Company 808 S.W. 15th Avenue 503/227-1616 800/424-9300 Porttand_Gregon97205 trUCRAAv .....-..�. _ I- GW GREAT WESTERN CHEMICAL CO. 5700 N.W. Front Ave. Portland, Oregon (503) 227-1616 SANICHEM roduct Information Bi LCA - 619 97210 LIQUID CAUSTIC ADDITIVE DESCRIPTION: LCA - 619 is a concentrated liquid additive for use in caustic solutions. LCA - 619 is designed to supply wetting action, mineral sequestration, provide some anti -corrosion properties, and aid rinsability in the food processing industry. FEATURES AND BENEFITS: RINSES FREELY - helps prevent caustic filming on equipment surfaces and allows faster rinsing of caustic solutions. POWERFUL WETTING PROPERTIES - provides penetrating action on soiled surfaces. CHELATED - sequesters and chelates troublesome minerals and metals. HEAT STABLE - for evaporators, H.T.S.T. units, flyers, blanchers, ultra high temperature equipment, etc. ECONOMICAL - mixes readily and is easy and economical -to use. VERSATILE - can be added to build shipments of caustic or injected separately in an automatic CIP system. COLD TEMPERATURE STABILIZED - will not salt out at lower temperatures. TYPICAL PROPERTIES: Appearance ................. Clear, brown liquid Alkalinity as Na2O to pH 4.3 ..... 0.3% Causticity as Na2O to pH 8.3 ..... 0.0% Specific Gravity @ 20 °C 1.208 pH of (as is) Solution 7.5 - 9.5 Density ................. 10.1lbs/gal Foaming Characteristics Low RECOMMENDED USES: LCA - 619 is recommended for any application where caustic is used for cleaning. Recommended for cold and hot CIP pipelines, H.T.S.T. units, evaporators, brew kettles and kegs, cookers, fryers, blanchers, fillers, and general food processing equipment. Improves caustic performance on most food soils in varying water conditions. i 1 VAE SYTy 'Tl4I -11RN�A;.-i 5700 N.W. Front Ave. Portland, Oregon 97210 (503) 227-1616 S A NN, C F'�UlA Product Inforn.nation Dulledn 17. -j-ACA 9 LIQUID CAUSTIC I-ODITI'VE, DESCRIVI-110-N: LCA - 619 is a couccntratetl liquid additiVe.l'im- use in caustic solut4ons.. LCA.:- 619 is &,4siga,Od to supply wming action, Ininet' al Soquestmatioll, p ovide sonic Z111tt-corl"os,oll properties, and aid rinsability in the food pioccsslin� iadu!TiTy. AINT) DENT-3-7--tTS: P I, surfaces and zdtm,Js favt-- P-rTITSES T-TIFEL-Y - he!ps prevent caustic 1:1-iiijig C-11 eTulpraen t surfaces is; ivi-g of cl-IUSLIC solutions. prowridas peretratinaon ileg odsu�f2ccs- CHELA.'A11D - Squcsl.ei-s; and ch(-Uv'es trcjublp.,;-ome alinenil's and metals. -yers, bla:ntchers, di Lra 11-�igh FEENT STARLIE, - for evaporawrs, F.I.T.S.T uidts, fi. temperature equipment, etc. ECONOT - I NUCAL - mixes readily and is easy and economical to use. VERSATILE - can be added to build shipments of caustic or injected separately in an automatic CPP System. ("OLD TENJTERAIURE STABTL.I=-zD - vidl not salt out at lower temperatures. T�TIIICAL PROPERTIES: Appearance ................. Clear, brown liquid Alkalinity as NCZO to p1171 4.3 ..... 0. 3 % Causticity as Na20 to pl-f. 8.3 ..... 0.0% Spccific Gfavity@20"C ..... E208 pH of (as is) '.`.iolution 7.5 -- 9J Density ................. M.1 lbs/gal Foaming Characteristics ..... T,ow RRCODNM�MMDEID -USEll LCA - 619 is -,-t:oramend,-,d for any applicaijon vvhc-7- Cwustdc, is useJ 160Y clea-T.dwy A 4 L cl d d C 1 P piliclil"', -,;, a J I U g,�, coc�c- fil lcf� M-'Q'St GO.: